||1-benzyl-4-phenyl-1H-1,2,3-triazole and glycidyl-4-phenyl-1,2,3-triazolyl polymer were synthesized by copper(I)-catalyzed 1,3-dipolar cycloaddition that called ‘Click Chemistry’. Benzyl azide and phenyl acetylene were used to prepare 1-benzyl-4-phenyl-1H-1,2,3-triazole. Glycidyl azide polymer(GAP) and phenyl acetylene were used to prepare glycidyl-4-phenyl-1,2,3-triazolyl polymer. Structure and composition of synthesized 1-benzyl-4-phenyl-1H-1,2,3-triazole and glycidyl-4-phenyl-1,2,3-triazolyl polymer were characterized by Fourier Transform Infrared Spectroscopy(FT-IR) and Proton Nuclear Magnetic Resonance Spectroscopy(1H-NMR). 94% yield with white powder and 74% yield with white powder were produced, respectively.