화학공학소재연구정보센터
학회 한국화학공학회
학술대회 2021년 봄 (04/21 ~ 04/23, 부산 BEXCO)
권호 27권 1호, p.810
발표분야 재료
제목 Catalyst-driven growth kinetics for control of crystalline structures of two-dimensional MoS2
초록 Catalysts play key roles to determine the growth kinetics of two-dimensional transition metal dichalcogenides by chemical vapor deposition. However, the roles of different catalytic intermediates on each growth step are still largely unknown. Here, we study the catalyst-assisted metal-organic chemical vapor deposition of monolayer MoS2 with different atomic/molecular elements, supplied by growth substrates. Na elements embedded in the substrates similarly enhance the growth rates, regardless of the surrounding mediums. On the other hand, the domain sizes can vary by an order of magnitude, depending on the composition of seed elements. Na-Mo-O eutectic alloys reduced the density of nuclei by Ostwald ripening, resulting in large MoS2 domains by vapor-liquid-solid mechanism. Growths mediated by different catalysts resulted in high crystalline films as electrical channel of field-effect transistor, and nano-crystalline flakes for enhanced hydrogen evolution reaction.
저자 최민영, 김철주
소속 포항공과대
키워드 화공재료
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