화학공학소재연구정보센터
학회 한국고분자학회
학술대회 2019년 가을 (10/09 ~ 10/11, 제주컨벤션센터)
권호 44권 2호
발표분야 분자전자 부문위원회 II
제목 The polymer solar cell efficiency over 10% based on siloxane-terminated side-chain polymer donor
초록 Halogenation atoms have been widely used into organic semiconductor materials to improve the photovoltaic device performance of polymer solar cells (PSCs). A novel wide-bandgap conjugated polymers (P1 and P2) was designed and synthesized which consists of BDT as donor and BDD as acceptor unit. Herein, chlorine and siloxane-terminated side chains are important strategies to enhance the absorption coefficient, solubility, dominated the energy losses and increasing the mobility of photoactive materials. Non-halogenated solvent processed for P2 polymer with IT-4F acceptor achieved the PCE of 10.52% [(Voc) of 0.85 V, (Jsc) of 17.50 mA/cm2, and (FF) of 70.78%] with effective surface modification treatment on ZnO layer. Whereas, the P1 polymer obtained PCE of 8.42%. Overall, the siloxane-terminated side chain with Cl designed polymer dedicated to device via effective surface modified treatment on ZnO layer yielded high performance of PSCs.
저자 타바마니 구굴라한트1, 김준영1, 제갈영순2, 진성호1
소속 1부산대, 2경일대
키워드 polymer solar cell; siloxane; side-chain
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