화학공학소재연구정보센터
학회 한국고분자학회
학술대회 2019년 봄 (04/10 ~ 04/12, 부산컨벤션센터(BEXCO))
권호 44권 1호
발표분야 기능성 고분자
제목 Conjugated polyquinoxaline-based photocatalyst: Generation of reactive oxygen species and organic compound oxidation
초록 We synthesized polyquinoxailnes(PQs) using fluorene unit as electron donor and quinoxaline derivatives unit as electron donor via Suzuki coupling polymerization. The PQs generated reactive oxygen species(ROS) under solar light irradiation. The ROS are chemically reactive species such as peroxide, superoxide, hydroxyl radical and singlet oxygen. Recently, many researchers are interested in the field of ROS-mediated photocatalysis because ROS present high reactivity to olefin and amine compounds. In this study, we investigated the photocatalysis efficiency of the PQs via conversion of benzylamine into N-benzylidene(phenyl)methanamine benzylamine by monitoring 1H NMR. Also, the photocatalytic activity of PQs was evaluated in the N,N-dimethyl-4-nitrosoaniline (RNO) dye. For practical use in the photocatalyst reaction, we fabricated a paper-based strips containing the PQs via simple wetting of filter paper in polymer solution.
저자 조선영, 이택승
소속 충남대
키워드 conjugated polymer; photocatalyst; photooxidation
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