화학공학소재연구정보센터
학회 한국고분자학회
학술대회 2019년 봄 (04/10 ~ 04/12, 부산컨벤션센터(BEXCO))
권호 44권 1호
발표분야 고분자구조 및 물성
제목 Star-Shaped Block Copolymers: Effective Polymer Gelators of High-Performance Gel Electrolytes for Electrochemical Devices
초록 Ion gels composed of copolymers and ionic liquids have attracted great interest as polymer gel electrolytes for various electrochemical applications. Here, we present highly robust ion gels based on a six-arm star-shaped block copolymer of (poly(methyl methacrylate)-b-polystyrene)6 and an ionic liquid of [EMI][TFSI]. Compared to typical ion gels based on linear PS-b-PMMA-b-PS, the (MS)6-based gels show mechanical moduli of more than twice under various strains. To demonstrate that (MS)6-based ion gels can serve as effective gel electrolytes for electrochemical applications, Ru(bpy)32+ is incorporated into the gels. In particular, flexible ECL devices based on (MS)6 gels exhibit high durability against bending deformation compared to devices with gels based on linear SMS having a similar molecular weight and a composition. This result implies that star-shaped block copolymers are effective gelators for achieving flexible/wearable electrochemical electronics.
저자 황희동, 신나리, 김진곤
소속 포항공과대
키워드 block copolymers; electrochemical displays; flexible electronics; ion gels; polymer gel electrolytes
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