화학공학소재연구정보센터
학회 한국공업화학회
학술대회 2017년 가을 (11/08 ~ 11/10, 부산 벡스코(BEXCO))
권호 21권 2호
발표분야 에너지저장변환_포스터
제목 Synthesis and Investigation of Ether free type Poly(p-phenylene) based Anion Exchange Membrane (AEM) for Use in Vandium Redox Flow battery
초록 Hydrocarbon-based anion exchange membranes (AEM) have been considered as one of the promising electrolytes for vanadium redox flow battery. However, typically, hydrocarbon-based anion exchange membranes display poor chemical stability due to the presence of V5+, which is a strong oxidizing agent in the VRFB system. Therefore, our group designed a robust AEM without aryl ether bonds to improve chemical stability and long-term durability. Herein, a series of poly(p-phenylene)s containing a quaternary ammonium group or imidazolium group were synthesized via Ni(0)-catalyzed coupling polymerization, benzylic bromination and in situ amination, successively. In particular, the chemical stability and VRFB performance of the synthesized membranes based on  poly(p-phenylene) with different functional groups were investigated.
저자 차민석1, 신상훈1, 홍수현1, 오성근2, 이장용1, 홍영택1
소속 1한국화학(연), 2한양대
키워드 Anion exchange membrane; Vanadium redox flow battery; Poly(p-phenylene)s;
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