화학공학소재연구정보센터
학회 한국공업화학회
학술대회 2017년 가을 (11/08 ~ 11/10, 부산 벡스코(BEXCO))
권호 21권 2호
발표분야 콜로이드계면화학_포스터
제목 Kinetics and sorption studies on the removal of cesium in water by magnetic hydrogel beads
초록 The Severe nuclear accident at the Fukushima Daiichi nuclear power station in 2011 released a huge amount of radioactive cesium into natural environments. Although commercial available Cs adsorbents have effective sorption property, they cannot be directly applied to natural environments because there is no easy way to collect them after use. To address this problem, we developed a magnetic beads composed of polyvinyl alcohol(PVA) hydrogel, magnetic nanoparticles, and commercial prussian blue to remove the cesium from water. To determine equilibrium sorption and kinetic parameters for different initial cesium ion concentrations, all the studies were conducted by a batch method. we found to be described the best by a Langmuir sorption isotherm. Sorption kinetics data were analysed, using different kinetic models. The results show that the sorption follows pseudo second-order reaction kinetics. Moreover, the beads selectively adsorbed Cs even in the presence of competing cations.
저자 황주리1, 박찬우2, 이근우2, 이경진1, 양희만2
소속 1충남대, 2한국원자력(연)
키워드 magnetic beads; cesium; sorption; kinetics
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