화학공학소재연구정보센터
학회 한국공업화학회
학술대회 2015년 봄 (04/29 ~ 05/01, BEXCO (부산))
권호 19권 1호
발표분야 (국제협력) 우수 외국인 연구자 세션
제목 Production of FDCA from HMF using Mixed Solvent System
초록 Furan-2, 5-dicarboxylic acid (FDCA), an alternative of terephthalic acid (TA), is widely used as intermediates for the polymers, fine chemicals, pharmaceuticals and agrochemicals. FDCA has many applications; however, it suffers from its low productivity. For the large scale production of FDCA, the process indeed needs to be improved. Here, we introduce the production of FDCA from HMF oxidation using mixed solvent system. The oxidation of HMF to produce FDCA has been carried wherein both alcohol and aldehyde groups of HMF react with molecular oxygen over the catalyst of metals/bromide (Co/Mn/Br). To achieve maximum yield of FDCA at complete conversion of HMF, the reaction conditions were optimized by varying the reaction temperature (from 130 – 180 o C), time (from 1 – 4 h) and pressure (from 600 – 900 Psi).
저자 Dinesh Kumar Mishra, 조진구, 소정은, 김용진
소속 한국생산기술(연)
키워드 5-hydroxymethyl-2-furfuraldehyde; oxidation
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