화학공학소재연구정보센터
Fuel, Vol.87, No.2, 232-243, 2008
Combustion of bio-oil ethanol blends at elevated pressure
This paper reports an investigation on the combustion performance of bio-oil/ethanol blends. Experiments were conducted in a constant volume vessel operating at a pressure of 25 bar and temperature 1100 K. Bio-oil produced via the fast pyrolysis of a spruce feedstock was blended to ethanol to form three stable blends containing 10%, 20% and 40% bio-oil by weight. In addition, ethanol and standard automotive grade diesel were tested as reference fuels. Measured vessel pressure was used in a single-zone heat release analysis, while two-colour optical pyrometry was used to investigate particle loading and temperature. Results show that for similar injections of fuel energy, use of up to 20'/0 bio-oil in ethanol has limited impact on the performance of ethanol while 40% bio-oil in ethanol produced instability in the pressure trace near the end of the combustion process. Burning rates are similar for blends and ethanol. Addition of bio-oil to ethanol was found to increase combustion generated particle load, and this increased with bio-oil concentration, but remained much lower than particle concentration in diesel. Addition of bio-oil also resulted in formation of char particles that appear as luminous clusters outside the boundary of the spray. This suggests these particles will cool rather than oxidize. The presence of unburnt char particles in large numbers may have consequences for bio-oil as an alternative diesel fuel. Crown Copyright (C) 2007 Published by Elsevier Ltd. All rights reserved.