화학공학소재연구정보센터
Journal of Applied Polymer Science, Vol.125, No.2, 1049-1058, 2012
Synthesis and characterization of nonlinear optical side-chain polyimides containing the thiadiazole chromophores
Thermally stable second-order nonlinear optical (NLO) polyimides were synthesized using a standard condensation polymerization technique. The polyimides were prepared from 4,4'-(hexafluoroisopropylidene)diphthalic anhydride (6FDA) and pyromellitic dianhydride (PMDA) with two aromatic azo- and diazo-diamine derivatives as the NLO chromophores. The resulting polyimides were characterized by FTIR, 1H-NMR, UV-vis spectroscopies, differential scanning calorimetry, thermogravimetric analysis, and gel permeation chromatography. The weight-average molecular weights of polyimides determined by gel permeation chromatography (GPC) were in the range of 32,100 to 39,300 (Mw/Mn = 1.581.74). All the polyimides exhibited an excellent solubility in many of the aprotic polar organic solvents, manifesting that these polyimides offer good processability. The glass transition temperature for the resulting polyimides was in the range of 152 to 194 degrees C and most of them showed high thermal stability. Particularly, the polyimides containing diazo group and PMDA backbone showed an enhanced thermal stability and glass transition temperature. The second harmonic generation (SHG) coefficients (d33) of the poled polyimide films range from 43.71 to 80.49 pm/V at 532 nm. Further, it is noticed that there was no SHG decay below 180 degrees C because of the partial main-chain character of the polyimide structure, which is acceptable for nonlinear optical device applications. (c) 2011 Wiley Periodicals, Inc. J Appl Polym Sci, 2012