화학공학소재연구정보센터
Journal of Industrial and Engineering Chemistry, Vol.18, No.4, 1353-1365, July, 2012
Kinetic study of the selective catalytic hydrogenation of 1,3-butadiene in a mixture of n-butenes
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The selective hydrogenation in liquid phase of 1,3-butadiene in the presence of n-butenes, over a commercial Pd/Al2O3 catalyst of the egg-shell type was studied. Experiments were carried out in a batch reactor at 44 ℃. Initial concentration were in the range of 1%-2% of 1,3-butadiene, up to 10% of 1-butene, trans-2-butene and cis-2-butene. Partial hydrogen pressures ( pH2 ) were between 1 and 8 atm. Two kinetic models were proposed to fit the experimental data. Both models give an adequate representation of the experimental data.
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