화학공학소재연구정보센터
Applied Surface Science, Vol.257, No.14, 5957-5960, 2011
Observation of ultra-long lifetime UV-induced infrared absorption in undoped and magnesium-doped congruent lithium niobate crystals
We report experimental observation of ultra-long lifetime UV-induced absorption in undoped and 5 mol.% Mg-doped congruent lithium niobate crystals between 400 nm and 2500nm wavelength range. The saturated absorption coefficient change in undoped congruent lithium niobate was about 3 to 7 times that in Mg-doped congruent lithium niobate in the mid-infrared spectrum. The UV-illuminated LiNbO3:Mg was fully recovered in the dark after 2 days, whereas the undoped congruent LiNbO3 still exhibited nontrivial infrared absorption. We attribute the cause of the UV-induced absorption to the creation of hole-trapped intermediate states O-near lithium vacancies. (C) 2011 Elsevier B. V. All rights reserved.