화학공학소재연구정보센터
Journal of Colloid and Interface Science, Vol.351, No.1, 239-247, 2010
Humic acid-inspired hybrid materials as heavy metal absorbents
Three SiO2-based materials were prepared via covalent immobilization of carboxyl groups (COOH), phenolic groups (GA), or humic acid on an SiO2 surface. Their sorbing properties were evaluated for removal of heavy metals (Pb2+, Cd2+, Cu2+, Zn2+, and Mg2+) from aqueous solution. The data show a significant improvement for metal uptake, compared to unmodified silica that can be attributed to the adsorption of metals to the deprotonated form of functional groups (COOH, GA, HA). The metal-uptake capacity of the SiO2-HA material was 10 times higher that those of the other two materials. The present data provide direct experimental proof that HA can be viewed and modeled as a combination of -COO and R-OH functional groups. (C) 2010 Elsevier Inc. All rights reserved.