화학공학소재연구정보센터
Applied Catalysis A: General, Vol.371, No.1-2, 114-120, 2009
Multiphase catalytic isomerisation of linoleic acid by transition metal complexes in ionic liquids
Methyl (ethyl) linoleate and soybean oil were efficiently transformed into their conjugated isomers (linoleic derivatives) by RuHCl(CO)(PPh3)(3) or RhCl(PPh3)(3) dissolved in ionic liquids (ILs), namely 1-n-butyl-3-methylimidazolium, N,N-methyl-n-butylpyrrolidinium and tetra-n-butylammonium cations associated with bromide (Br-), hexafluorophosphate (PF6-) and bis(trifluoromethylsulfonyl)imidate (NTf2-) anions. For example, methyl linoleate was converted to a mixture of conjugated products (E,Z,Z,Z and EX linoleic methyl esters) in up to 80% yield when catalyzed by RuHClCO(PPh3)(3) in BMI center dot NTf2 at 80 degrees C. In the case of RhCl(PPh3)(3)/SnCl2 associated with BMI center dot NTf2, complete conversion of methyl or ethyl linoleate was observed after 24 h at 60 degrees C, with an 85% selectivity for Z,E isomers. However, these reactions were accompanied by extensive transesterification side reactions between the methyl esters or triglycerides. The transesterification side reactions were strongly dependent on the anion of the ionic liquid. For example, extensive ethyl esters were formed in the reaction performed with RhCl(PPh3)(3)/SnCl2 associated with ethanol in 1-n-butyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imidate IL (65%). Conversely, the reaction performed using the simple salt NBu4 center dot Br in combination with RhCl(PPh3)(3)/SnCl2 showed the most impressive results, rendering a more active catalytic system (97% of isomerised soybean oil after 24 h at 60 degrees C) while preventing transesterification. The use of the Ru and Rh catalyst precursors in combination with ionophilic phosphines decreased metal leaching into the product phase. (C) 2009 Elsevier B.V. All rights reserved.