Korean Journal of Chemical Engineering, Vol.7, No.2, 145-147, April, 1990
SELECTIVE CONVERSION OF NITROBENZENE TO PHENYLCARBAMATES CATALYZED BY Pd(II) AND HETEROPOLYACIDS
A homogeneous catalyst system of Pd(II) and a heteropolyacid(HPA) converts nitrobenzene to N-phenylcarbamate with a selectivity of 96.3% at 100% nitrobenzene conversion, which appears to be the best value known in the literature. However, the catalyst forms solid deposits during the reaction.
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