화학공학소재연구정보센터
Separation and Purification Technology, Vol.61, No.3, 398-403, 2008
Formaldehyde and acetaldehyde adsorption properties of heat-treated rice husks
Rice husk (RH) was converted into an adsorbent to remove two types of aldehyde vapor. Japanese RH was carbonized at 250-800 degrees C in N-2 or activated at 875 degrees C in M. The carbonized and activated RHs were exposed to formaldehyde vapor at 1.0 vol. ppm or acetaldehyde vapor at 100 vol. ppm (both in N-2 carrier gas) in enclosed 5-L gas-sampling bags. The RH activated at 875 degrees C showed the fastest decrease in formaldehyde and acetaldehyde concentrations in the bags. The rate of aldehyde adsorption was higher for activated RH than for commercial granular coconut-shell activated carbon (GCSAC), whereas the specific surface area and total pore volume for activated RH (466.9 m(2)/g and 0.35 cm(3)/g) were much lower than for GCSAC (1119.7 m(2)/g and 0.57 cm(3)/g). The surface basicity of activated RH and RH carbonized at high temperature, attributed to intrinsic inorganic K and Ca compounds, enhanced the surface uptake of aldehydes. (C) 2007 Elsevier B.V. All rights reserved.