화학공학소재연구정보센터
Electrochimica Acta, Vol.54, No.2, 334-340, 2008
Facile electrosynthesis of nitro-group-substituted oligopyrene with bicolored emission
Nitro-group-substituted oligopyrene (ONP) film with fairly high electrical conductivity (1.25 x 10(-1) S cm(-1)) and good thermal stability was electrochemically synthesized by direct anodic oxidation of its monomer 1-nitropyrene (NP) in boron trifluoride diethyl etherate (BFEE). The oxidation potential of NP in this medium was determined to be 1.12V vs. SCE, which was lower than that in acetonitrile +0.1 mol L-1 Bu4NBF4 (1.27V vs. SCE). ONP films obtained from this medium showed good redox activity and structural stability in both BFEE and concentrated sulfuric acid. Fourier transform infrared spectra and theoretical calculations showed that the electropolymerization of the NP monomer mainly occurred at the C(3), C(6) and C(8) positions. The fluorescence spectra suggested that soluble ONP emits strong blue or green fluorescence when excited at 402 nm or 504 nm, respectively. Scanning electron microscopy showed that highly crystalline nitro-group-substituted oligopyrene was formed on the electrode surface. All these results indicate that as-prepared ONP film has many potential applications in various fields. (c) 2008 Elsevier Ltd. All rights reserved.