화학공학소재연구정보센터
Electrochemical and Solid State Letters, Vol.10, No.1, A1-A4, 2007
Improvement of electrochemical properties of natural graphite anode materials with an ovoid morphology by AlPO4 coating
AlPO4-coated natural graphite was prepared by mixing precipitated AlPO4 nanoparticles with natural graphite (NG) powders that had an ovoid morphology in water, followed by vacuum-drying at 150 degrees C for 24 h. This simple coating method did not require any further heat-treatment above 400 degrees C, which is an essential process for the sol-gel driven coating methods (Al2O3 and ZrO2). The electrochemical properties of the AlPO4-coated NG were compared with bare and pitch-coated samples and are reported. Impedance analysis revealed that, although the value of the surface film impedance of the AlPO4-coated sample was 2.4 times larger than the bare NG, its charge-transfer (CT) impedance was 7.5 times smaller than the bare NG. Consequently, we believe that CT was a critical factor that affected the cycle life performance of the sample. (c) 2006 The Electrochemical Society.