화학공학소재연구정보센터
Electrochimica Acta, Vol.39, No.6, 793-799, 1994
A Contribution to the Mechanism of Reduced CO2 Adsorbates Electrooxidation from Combined Spectroelectrochemical and Voltammetric Data
The nature of reduced CO2 adsorbates, as well as the mechanisms for their electro-oxidation on platinum, have been reviewed through the light of new experimental data obtained by cyclic voltammetry and by Fourier transform infrared reflectance spectroscopy. Three different "reduced" CO2 adsorbates are described as "ensembles". It is suggested that they involve different extents of adsorbed entities, among which weakly bound and strongly bound hydrogen atoms play the most important role.