화학공학소재연구정보센터
Applied Surface Science, Vol.203, 39-42, 2003
Doubly versus singly positively charged oxygen ions back-scattered from a silicon surface under dynamic O-2(+) bombardment
Mass-resolved (and emission-charge-state-resolved) low-energy ion back-scattering during dynamic O-2(+) bombardment of a silicon surface was applied in a Cameca IMS-3f secondary ion mass spectrometry (SIMS) instrument to determine the bombarding energy dependence of the ratio of back-scattered O-2(+), versus O+. While the ratio of O-2(+) versus O+ drops significantly at reduced bombarding energies, O-2(+) back-scattered from silicon was still detectable at an impact energy (in the lab frame) as low as about 1.6 keV per oxygen atom. Assuming neutralization prior to impact, O-2(+) ion formation in an asymmetric O-16 --> Si-28 collision is expected to take place via 'collisional double ionization' (i.e. by promotion of two outer O 2p electrons) rather than by the production of an inner-shell (O 2s or O 1s) core hole followed by Auger-type de-excitation during or after ejection. A molecular orbital (MO) correlation diagram calculated for a binary 'head-on' O-Si collision supports this interpretation. (C) 2002 Elsevier Science B.V. All rights reserved.