화학공학소재연구정보센터
Applied Surface Science, Vol.196, No.1-4, 126-137, 2002
Effects of oxidation on surface heterogeneity of carbosils
Carbon-silica adsorbents (carbosils), prepared by pyrolysis of methylene chloride (CH2Cl2) on the surface of a porous silica gel, were subjected to an oxidizing hydrothermal treatment (HTT) at 200 degreesC, using a hydrogen peroxide water solution as a modification medium. Conventional nitrogen adsorption volumetry and low-pressure argon and nitrogen adsorption techniques were used to analyze and compare textural properties and surface heterogeneity of initial and hydrothermally treated samples. In the presence of carbon, the mesoporous network of silica gel is protected from the massive collapse generally observed after oxidizing HTT. For carbosils, some changes occur during HTT, leading to a slight decrease of specific surface areas accompanied by an increase in mean mesopore size. The argon and nitrogen condensation energy distributions, derived from low-pressure adsorption experiments, indicate that both silica and pyrocarbon materials were modified during HTT. Depolymerization and recondensation processes occur for silica, creating new silica surfaces. These processes are responsible of the decrease in specific surface areas. For pyrocarbon, similar depolymerization and recondensation processes probably occur, creating new and high-energy surface sites. (C) 2002 Elsevier Science B.V. All rights reserved.