화학공학소재연구정보센터
Chemistry Letters, Vol.34, No.3, 372-373, 2005
Stereoselective synthesis of delta-Amino-beta',gamma-hydroxy-beta,gamma-unsaturated esters by the samarium(II) iodide-mediated aldol reaction of aldehydes with gamma,delta-aziridiny-alpha,beta-unsaturated esters
delta-Amino-beta'-hydroxy-beta, gamma-unsaturated esters were stereoselectively synthesized by the aldol reaction of aldehydes with samarium enolates generated by aziridine-fragmentation of gamma,delta-aziri dinyl-alpha, beta-unsaturated esters using two moles of samarium(II) iodide.