화학공학소재연구정보센터
Journal of Physical Chemistry A, Vol.109, No.9, 1810-1814, 2005
Effect of OH internal torsion on the OH-stretching spectrum of cis,cis-HOONO
We show that a simple two-dimensional vibrational model can explain most of the features observed in the first and second OH-stretching overtone region of the room temperature cis,cis-HOONO spectrum. The model uses ab initio calculated parameters and includes the OH-stretching mode coupled to the internal torsion of the OH group.