화학공학소재연구정보센터
Electrochimica Acta, Vol.50, No.10, 2125-2134, 2005
Single-ion conducting polymer-silicate nanocomposite electrolytes for lithium battery applications
Solid-state polymer-silicate nanocomposite electrolytes based on an amorphous polymer poly [(oxyethylene)(8) methacrylate], POEM, and lithium montmorillonite clay were fabricated and characterized to investigate the feasibility of their use as 'salt-free' electrolytes in lithium polymer batteries. X-ray scattering and transmission electron microscopy Studies indicate the formation of an intercalated morphology in the nanocomposites due to favorable interactions between the polymer matrix and the clay. The morphology of the nanocomposite is intricately linked to the amount of silicate in the system. At low clay contents, dynamic rheological testing verifies that silicate incorporation enhances the mechanical properties of POEM, while impedance spectroscopy shows an improvement in electrical properties. With clay content greater than or equal to 15 wt.%, mechanical properties are further improved but the formation of an apparent superlattice structure correlates with a loss in the electrical properties of the nanocomposite. The use of suitably modified clays in nanocomposites with high clay contents eliminates this superstructure formation, yielding materials with enhanced performance. (C) 2004 Elsevier Ltd. All rights reserved.