화학공학소재연구정보센터
Thin Solid Films, Vol.471, No.1-2, 40-47, 2005
Pulsed laser deposition of cobalt ferrite in a reactive O-2 : N-2 atmosphere: effect of the deposition pressure and temperature
Thin films of CoFe2O4 have been fabricated by pulsed laser ablation of a metallic CoFe2 target at two different temperatures (200 and 400 degreesC) and in various O-2:N-2, 20:80 pressures [from 0.7 Pa (5 x 10(-3) Torr) up to 26.7 Pa (2 x 10(-1) Torr)]. Too low pressures resulted in an insufficient oxidation of the deposited material and an antiferromagnetic (Fe,Co)O phase is observed together with CoFe2O4. A minimum pressure of 6.7 Pa was found necessary to obtain pure CoFe2O4 films with magnetic properties close to the bulk. The higher the pressure and the temperature, the larger was the roughness of the films. The optimum deposition temperature and pressure to obtain flat (3 nm rms roughness) CoFe2O4 films were, respectively, 200 degreesC and 6.7 Pa. (C) 2004 Elsevier B.V. All rights reserved.