화학공학소재연구정보센터
Macromolecules, Vol.36, No.12, 4582-4588, 2003
Independent control of rigidity and toughness of polymeric hydrogels
Refined control over the mechanical properties of hydrogel-based materials has increased as these materials have found broader application. We investigated various aspects of gel cross-linking to independently regulate the elastic modulus (E) and toughness M. Alginate hydrogels were chosen as a model system, since alginate can be gelled via ionic or covalent cross-linking, and its block structure dictates the structure of ionic cross-links. Increasing the density of covalent cross-links increased E but led to more brittle gels. In contrast, increasing the density of ionic cross-links and length of the blocks responsible for the cross-linking increased both E and W. Oscillatory shear measurements suggested that ionic cross-links and their length were important in dissipating the energy of deformation due to a partial and stepwise de-cross-linking. In contrast, covalently cross-linked gels underwent energy accumulation. This study demonstrates a novel approach to independently control different mechanical properties of gels.