화학공학소재연구정보센터
Thermochimica Acta, Vol.400, No.1-2, 69-77, 2003
Excess molar enthalpies of the ternary mixtures: (diisopropyl ether or 2-methyltetrahydrofuran) plus cyclohexane plus n-heptane at 298.15 K
Microcalorimetric measurements of excess molar enthalpies, at 298.15 K, are reported for the two ternary systems formed by mixing either diisopropyl ether or 2-methyltetrahydrofuran with binary mixtures of cyclohexane and n-heptane. Smooth representations of the results are presented and used to construct constant excess molar enthalpy contours on Roozeboom diagrams. It is shown that useful estimates of the ternary enthalpies can be obtained from the Liebermann and Fried model, using only the physical properties of the components and their binary mixtures.