Journal of the Korean Industrial and Engineering Chemistry, Vol.14, No.3, 365-370, May, 2003
다양한 기능성 도판트로 도핑된 가용성 폴리피롤의 용매화 효과 및 특성
Solvent Effect and Characterization of Soluble Polypyrrole Doped with Various Functional Dopants
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초록
극성 작용기와 비극성 작용기를 동시에 갖는 기능성 도판트인 sodium di(2-ethylhexyl) sulfosuccinate (DEHSNa), sodium dioleylsulfosuccinate (DOSNa), sodium butylnaphthalenesulfonate (BNSNa)을 사용하여 극성 용매(DMSO, DMF, NMP 등)와 비극성 용매(클로로포름, dichloromethane 등)에 가용성인 폴리피롤(Ppy-DEHS, Ppy-DOS, Ppy-NBS)을 합성하였다. 극성 작용기로 도핑된 가용성 Ppy-DEHS 분말의 용해도는 상대적으로 비극성 용매보다( ~ 6 wt%/vol.) 극성 용매에서( ~ 11 wt%/vol.) 더 높게 나타났고, 이들 용매로부터 제조된 필름의 전기전도도도 또한 극성 용매에서 제조된 필름이(4 S/cm)비 극성 용매에서 제조된 필름보다 (2 x 10-2 S/cm) 더 높게 나타났다. 그러나, 비극성 작용기를 갖는 도판트로 도핑된 가용성 Ppy-DOS, Ppy-BNS의 경우, 상대적으로 비극성 용매인 클로로포름내에서 용해도가(6 ~ 9 wt%/vol.)극성용매 (DMSO, DMF etc. 3 ~ 4 wt%/vol.)인 경우보다 높게 나타났다. 다양한 유기용매에서 제조된 Ppy-DEHS, Ppy-DOS, Ppy-NBS 필름의 전하전달은 모두 3차원 VRH model{σdc(T) = σo exp[-(To/T)1/4]}에 부합하였다.
Polypyrroles (Ppy-DEHS, Ppy-DOS, Ppy-BNS, etc.) soluble in polar (DMSO, DMF, NMP, etc.) and non-polar (chloroform, dichloromethane, etc.) organic solvents were synthesized using functional doping agents that have both polar and non polar functional groups; sodium di(2-ethylhexyl) sulfosuccinate (DEHSNa), sodium dioleylsulfosuccinate (DOSNa), and sodium butylnaphthalenesulfonate (BNSNa). Soluble Ppy-DEHS powder doped with polar functional group dopant showed a higher solubility in polar solvent ( ~ 11 wt%/vol.) than in non polar solvent ( ~ 6 wt%/vol.). Free standing film (4 S/cm) cast from polar solvent showed a higher electrical conductivity than that cast from non polar solvent (2 x 10-2 S/cm). Soluble Ppy-DOS and Ppy-BNS powders doped with non polar functional group dopant showed a higher solubility in non polar solvent (chloroform, 6 ~ 9 wt%/vol.) than in polar solvent (DMSO, DMF etc. 3 ~ 4 wt%/vol.). For the Ppy-DEHS, Ppy-DOS and Ppy-BNS films cast from various organic solvents, Three Dimensional Various Range Hopping model (3D VRH ; {σdc(T) = σo exp[-(To/T)1/4]}) was used to fit the results of temperature dependence of electrical conductivity measurement.
Keywords:soluble polypyrrole;functional doping agents;sodium dioleylsulfosuccinate;sodium butylnaphthalenesulfonate sodium di(2-ethylhexyl) sulfosuccinate
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