화학공학소재연구정보센터
Thin Solid Films, Vol.340, No.1-2, 33-39, 1999
Micro-scratch analysis and mechanical properties of plasma-deposited silicon-based coatings on polymer substrates
Advanced optical applications require multifunctional coatings with specific mechanical properties, such as resistance to damage and good adhesion to different types of substrates, including polymers. In the present study we deposited amorphous hydrogenated silicon nitride (SiN1.3) and oxide (SiO2) films on polycarbonate and on silicon substrates by plasma enhanced chemical vapor deposition (PECVD), using a dual-mode microwave/radio frequency plasma system. The film adhesion was determined by the micro-scratch test. Depth-sensing indentation and substrate curvature measurements were used to evaluate the microhardness. Young's modulus and residual stresses of the films. The adhesion strength, represented by the critical load, L-c, when the film starts to delaminate, was determined as a function of the substrate material and the energy of bombarding ions. A direct correlation between the L-c values and the mechanical properties of the films was found. The formation of different crack patterns in the coatings during the scratch procedure is explained in terms of stress release mechanism depending on the mechanical properties of the film, the substrate and the interface region. In addition, different models applicable to the evaluation of the work of adhesion in the case of hard coatings on soft substrates are critically reviewed.