화학공학소재연구정보센터
Polymer, Vol.36, No.20, 3949-3954, 1995
Functional Copolymers of Isobutylene and Acrylic Ester
Reactive copolymers of isobutylene and acrylic ester were successfully synthesized by the incorporation of acryloyl chloride or maleic anhydride into alternating copolymers of isobutylene and acrylic ester by means of complexed copolymerization catalysed with alkylboron halide. The terpolymers of isobutylene, acrylic ester and acryloyl chloride (AILM) and isobutylene, acrylic ester and maleic anhydride (AIHM) reacted with many compounds. Via the polymer reactions based on AILM and AIHM, various functional copolymers of isobutylene and acrylic ester were synthesized, which contained carboxyl group, amide group, hydroxyl group, nitrile group, epoxy group and so forth on the pendant of the polymer chains.