화학공학소재연구정보센터
Molecular Crystals and Liquid Crystals Science and Technology. Section A. Molecular Crystals and Liquid Crystals, Vol.285, 63-68, 1996
Unusual Conductive Behavior of (BEDT-TTF)(3)Cl-2 Hydrate Salts
The ion-radical salt (BEDT-TTF)(3)Cl-2 . 5H(2)O has been prepared through electro-crystallization using halocarbons as a solvent in the presence of an aliquot of water. The crystal structure was characterized by a multi-layered structure consists of organic layers of a donor stack and inorganic layers of hydrated chloride ions. When the resistivity was measured, the salt showed a rectifying effect. This effect may be caused by the external field-induced structural transition of chloride ions coupled with the change of a hydration scheme.