화학공학소재연구정보센터
Molecular Crystals and Liquid Crystals Science and Technology. Section A. Molecular Crystals and Liquid Crystals, Vol.276, 241-246, 1996
Chiral Lattice-Controlled Asymmetric (Beta-Alpha)Photoisomerization of 2-Substituted Ethyl Cobaloxime Complexes
Chiral lattice-controlled asymmetric photoisomerization of 2-methoxycarbonylethyl, 2-carbamoylethyl, 2-(N-methylcarbamoyl)ethyl and 2-(N-phenylcarbamoyl)ethyl cobaloxime complexes was found to occur which afforded corresponding, optically active 1-substituted ethyl cobaloxime complexes in enantioselectivities ranging from 4 to 69%ee.