화학공학소재연구정보센터
Molecular Crystals and Liquid Crystals Science and Technology. Section A. Molecular Crystals and Liquid Crystals, Vol.276, 235-240, 1996
Mechanism of Solid-State Racemization for Optically-Active Alkyl Cobaloxime Complexes - Synthesis and Solid-State Reaction of Deuterium-Labeled Complexes
The deutelium-labeled chiral 1,2-disubstituted ethyl cobaloxime complexes were synthesized, and the rate constants of the solid-state photoracemization and photoisomerization of these complexes were determined. The reaction mechanism for the solid-state photoracemization was elucidated by rationalization of these results.