화학공학소재연구정보센터
Applied Catalysis A: General, Vol.108, No.1, L1-L6, 1994
Selective Decomposition of Cyclohexyl Hydroperoxide to Cyclohexanone Catalyzed by Chromium Aluminophosphate-5
Chromium substituted aluminophosphate-5 is an active and recyclable catalyst for the selective decomposition of secondary alkyl hydroperoxides to the corresponding ketones. This has practical utility in the conversion of cyclohexane to cyclohexanone. Tert-alkyl hydroperoxides give primarily the corresponding alcohols and dioxygen.