화학공학소재연구정보센터
Macromolecular Research, Vol.31, No.6, 583-592, June, 2023
Synthesis and characterization of aromatic poly(phosphonate)s, poly(thiophosphonate)s, and poly(selenophosphonate)s for high refractive index
Highly refractive poly(phosphonate)s (BPOP), poly(thiophosphonate)s (BPTP), and poly(selenophosphonate)s (BPSP) with aromatic backbones were prepared by the polycondensation of phosphonic dichlorides and diols. The polymers have high thermal properties including high thermal properties (Td5% > 400 °C), glass transition temperature (Tg = 76 ~ 157 °C), and high optical properties such as transparency at 400 nm of over 80% for films of ca. 10 μm thickness, and a refractive index in the range of 1.633–1.675. In particular, BPSP exhibited a high refractive index (1.675) with low birefringence (0.0025) due to the heavy atom effect of selenium.