화학공학소재연구정보센터
Journal of Industrial and Engineering Chemistry, Vol.118, 383-392, February, 2022
Designing cactus-like Fe-P doped CoNi-S arrays as highly efficient electrocatalyst for overall water splitting
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Exploring high activity, stable and low-cost electrocatalysts are of great importance for high-efficient hydrogen production via water splitting. Herein, a cactus-like Fe, P co-doped CoNi-S arraywas constructed via facile hydrothermal reaction and subsequently sulfuration and phosphorization process. Benefiting from the strong synergistic effects of different components, high conductivity of bimetallic sulfide, 3D cactus-like architecture with rich channels for mass/charge transport, and Fe and P co-doping with electron structure regulation, the as-prepared Fe, P-NiCo2S4/NF presents superior electrocatalytic activity with low overpotentials of 139 and 290 mV to drive the current density of 10 and 40 mA cm-2 for HER and OER, respectively. Meanwhile, it also manifests the distinguished durability for over 60 h in alkaline media. Notably, when integrating in a two-electrode electrolytic cell with Fe, P-CoNi-S, a reduced operation voltage of 1.55 V is required to reach 10 mA cm-2, which is superior to precious metal-based Pt/C/NF//RuO2/NF counterparts. Impressively, it can also be driven by sustainable solar and thermal energies motivated Stirling engine. This work offers a universal strategy for designing high-activity and durable electrocatalysts by dual doping heteroatoms and synergistic interface engineering.
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