화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Journal of Industrial and Engineering Chemistry, Vol.118, 170-180, February, 2023
DOI10.1016/j.jiec.2022.11.002  Export Citation
Quasi-Fe-/Zn-phthalocyanine polymer derived 2D FeANAC single-atom catalyst for highly efficient ORR and H2O2 sensing
Jingshun Shen, Qi Liu, Qiqi Sun, Jianwei Ren1, Xue Liu, Zuoxu Xiao1, Chuanwang Xing1, Yuexing Zhang2, †, Guangwu Yang†, and Yanli Chen†
  • School of Materials Science and Engineering, China University of Petroleum (East China), Qingdao 266580, PR China
  • 1College of Chemistry and Chemical Engineering, China University of Petroleum (East China), Qingdao 266580, PR China
  • 2School of Chemistry and Chemical Engineering, Dezhou University, Dezhou 253023, PR China
E-mail:, ,
A novel two-dimensional (2D) single-atom Fe/N/C catalyst (Fe1Zn30NCPDI) has been prepared upon pyrolyzing a well-designed quasi-Fe-/Zn-phthalocyanine-based polymer (qFePc1@qZnPc30@PDI). In the qFePc1@qZnPc30@PDI precursor, qFePc moieties containing Fe-N4 sites are efficiently segregated by lots of qZnPc moieties connected together by perylene linkers, which not only leads to the larger specific area in the resulting Fe1Zn30NCPDI but more importantly ensures the in-situ formation of Fe-N4 sites on the self-supporting 2D N-doped carbon backbone. Impressively, Fe1Zn30NCPDI exhibites its superior oxygen reduction reaction (ORR) electro-catalytic activity and peroxidase (POD)-like activity. For ORR in an alkaline medium, it exhibites a much higher onset potential of 0.97 V and half-wave potential of 0.89 V than 20 wt% Pt/C catalyst with good durability of 92 % retention rate after 20000 s. And, Fe1Zn30NCPDI also shows better peak power density (86 mW cm-2) compared with 20 wt% Pt/C in Zn-air battery. Benefiting from the specific POD-like activity of Fe-N4, the Fe1Zn30NCPDI also shows excellent and selective performance in colorimetric H2O2 sensing, with the ultrafast response (30 s), a low limit of detection (10 nM), and good robustness. This work sheds light on a promising design concept for synthesizing 2D polymer-derived single-atom multifunctional catalysts.
Keywords:Quasi-phthalocyanine-PDI-based polymer;Fe-N4 sites;2D planar;ORR Peroxidase-like
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