화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Journal of Industrial and Engineering Chemistry, Vol.117, 371-385, January, 2023
DOI10.1016/j.jiec.2022.10.025  Export Citation
Thermal transformation of copper incorporated hydrotalcite-derived oxides and their catalytic activity for ethanol dehydrogenation
Artit Ausavasukhi†, Nattanitcha Krukrathok, and Pancheewa Singthaisong
  • Department of Applied Chemistry, Faculty of Sciences and Liberal Arts, Rajamangala University of Technology Isan, Nakhon Ratchasima 30000, Thailand
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Thermal transformation of copper incorporated hydrotalcite-derived oxides is investigated in ethanol dehydrogenation. Among the copper supported catalyst c-10Cu/HT600 prepared by impregnation of thermally treated hydrotalcite at 600 ℃ with Cu(NO3)2 solution followed by a calcination provides a high catalytic activity, selectivity and stability. XRD, DR-UV, TGA, H2-TPR, CO2-TPD, TEM and XPS techniques reveal that the nature of the copper species depended on the thermal treatment process and support. Such treatment at high temperatures yields a homogeneous dispersion mixed metal oxide. After copper incorporation generated CuAl2O4 spinel structure linked to the copper oxide species can suppress copper agglomeration leading to the catalytic stability. Moreover, the c-10Cu/HT600 catalyst can provide a high activity and high selectivity to acetaldehyde even at low reaction temperatures (200 ℃). However, the copper species may agglomerate to form relatively larger clusters upon increasing metal loading leading to the deactivation.
Keywords:Copper species;Thermal treatment;Ethanol dehydrogenation;Spinel structure;Hydrotalcite-derived oxides
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