화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Polymer(Korea), Vol.46, No.6, 766-774, November, 2022
DOI10.7317/pk.2022.46.6.766  Export Citation
Diisocyanate와 Diamine의 구조가 미치는 Epoxy 말단을 갖는 우레탄 올리고머 기반 탄성체의 물리적 특성 연구
Physical and Physico-mechanical Properties of Elastomers Based on Urethane Oligomers with Terminal Epoxy Groups as Affected by the Structure of Diisocyanates and Diamines
Anna V. Savchuk†, Aleksey I. Slobodinyuk, Valery Yu. Senichev, and Vladimir N. Strelnikov
  • Institute of Technical Chemistry of Ural Branch of the RAS as Affiliated Branch of Perm Federal Research Center of Ural Branch of the RAS Acad., Korolev St. 3, 614013 Perm, Russian Federation
E-mail:
There were investigated physical and physico-mechanical properties of elastomers based on three series of epoxy-terminated oligomers based on differently structured diisocyanates and diamines. The use of 3-isocyanatomethyl-3,5,5-trimethylcyclohexyl isocyanate enabled better strength properties to be obtained owing to the implementation of the strengthening effect. Also, there was elicited a positive influence of an increase in the content of 3-aminomethyl-3,5,5-trimethylcyclohexylamine in a mixture of hardeners on the strength of elastomers; it was associated with enhancing polarity of a polymer chain, therewith giving rise to changes in the phase separation degree.
Keywords:hard segments;soft segments;Fourier transform infrared spectrum;swelling;polyurethane;oligoetherurethane diepoxide;network density;glass transition temperature;physical and mechanical properties;phase separation
  1. Hepburn C, Polyurethane Elastomers; 2nd ed. Elsevier Science Publishers Ltd.: London, 2012.
  2. Prisacariu C, Polyurethane Elastomers from Morphology to Mechanical Aspects. Springer: New York, 2011.
  3. Randall D, Lee S, The Polyurethanes Book; Wiley: New York, 2003.
  4. Saunders JH, Frish KG, Polyurethanes. John Wiley and Sons: New York - London, 1968.
  5. Omel'chenko SI, Kadurina TI, Modified Polyurethanes. Naukova Dumka: Kyiv, 1983.
  6. Harkal UD, Muehlberg AJ, Edwards PA, Webster DC, J. Coat. Technol., 8, 735 (2011)
  7. Hsia HC, Ma CCM, Chen DS, Macromol. Mater. Eng., 220, 133 (1994)
  8. Harkal UD, Muehlberg AJ, Li J, Garrett JT, Webster DC, J. Coat. Technol., 7, 531 (2010)
  9. Makarova MA, Slobodinyuk AI, Tereshatov VV, Volkova ER, Kisel'kov DM, Polym. Sci. Ser. D, 7, 166 (2014)
  10. Sidorov OI, Kapustin SA, Shragin DI, Muzafarov AM, Sidorova NI, Pleshakov DV, Polym. Sci. Ser. D, 10, 322 (2017)
  11. Senichev VY, Slobodinyuk AI, Slobodinyuk DG, Savchuk AV, Kulakova MV, Oshchepkova TE, Borisova IA, Russ. J. Appl. Chem., 9, 1172 (2020)
  12. Tereshatov VV, Senichev VY, J. Macromol. Sci. Part B, 54, 365 (2015)
  13. Tereshatov VV, Russ. J. Appl. Chem., 83, 1341 (2010)
  14. Tereshatov VV, Tereshatova EN, Volkova ER, Polym. Sci., 37, 1881 (1995)
  15. Tereshatov VV, Tereshatova EN, Makarova MA, Tereshatov SV, Polym. Sci. Ser. A, 44, 275 (2002)
  16. Tereshatov VV, Vnutskikh ZA, Slobodinyuk AI, Makarova MA, Senichev VY, J. Elastomer Plast., 4, 289 (2016)
  17. Tereshatov VV, Makarova MA, Senichev VY, Volkova ER, Vnutskikh ZA, Slobodinyuk AI, Colloid Polym. Sci., 1, 153 (2015)
  18. Tereshatov VV, Makarova MA, Senichev VY, Slobodinyuk AI, Colloid Polym. Sci., 7, 641 (2012)
  19. Strel'nikov VN, Senichev VY, Slobodinyuk AI, Savchuk AV, Volkova ER, Makarova MA, Nechaev AI, Krasnosel’skikh SF, Ukhin KO, Russ. J. Appl. Chem., 91, 463 (2018)
  20. Strel'nikov VN, Senichev VY, Slobodinyuk AI, Savchuk AV, Volkova ER, Int. J. Polym. Sci., 2019 (2019)
  21. Vatulev VN, Laptii SV, Kercha UU, Infrared Spectra and Structure of Polyurethanes. Naukova Dumka: Kyiv, 1987.
  22. Sun W, Yan X, Zhu X, Polym. Bull., 69, 621 (2012)
  23. Fedoseev MS, Devyaterikov DM, Rybina GV, Meshechkina AE, Russ. J. Appl. Chem., 86, 1441 (2013)
  24. Strel'nikov VN, Senichev VY, Slobodinyuk AI, Savchuk AV, Volkova ER, Makarova MA, Belov YL, Derzhavinskaya LF, Selivanova DG, Russ. J. Appl. Chem., 91, 1937 (2018)
  25. Bakirova IN, Kirillova AS, Russ. J. Appl. Chem., 86, 1399 (2013)
  26. Socrates G, Infrared and Raman Characteristic Group Frequencies: Tables and Charts; John Wiley & Sons: Chichester, New York, 2004.
  27. Senichev VY, Slobodinyuk AI, Makarova MA, Savchuk AV, Pogoreltsev EV, J. Phys.-Conf. Ser., 1399, 044060 (2019)
  28. Bagdi K, Molnar K, Wacha A, Bota A, Pukánszky B, Polym. Int., 60, 529 (2011)
  29. Van Krevelen DW, Properties of Polymers: Their Correlation with Chemical Structure; Their Numerical Estimation and Prediction from Additive Group Contributions. 4th ed., Elsevier: Amsterdam, 2009.
  30. Malkin AY, Begishev VP, Chemical Molding of Polymers; Moscow, Khimia, 1991.
  31. Redman RP, Developments in Polyurethane-1. Applied Science Publishers Ltd.: London, 1978.
  32. Askadskii AA, Computational Materials Science of Polymers. Cambridge Int Science Publishing: Cambridge, 2003.
  33. George W, Handbook of Solvents, Volume 1: Properties, 3rd ed.; Elsevier: Amsterdam, 2019.
  34. Mills A, Monaf L, Analyst, 121, 535 (1996)