화학공학소재연구정보센터
Journal of Industrial and Engineering Chemistry, Vol.116, 339-350, December, 2022
Simultaneously photocatalytic removal of Cr(VI) and metronidazole by asynchronous cross-linked modified sodium alginate
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Conventional photocatalysts for environmental applications are mainly transitional metal compounds or precious metal nanoparticles, which suffer from weak pollutant adsorption performance, thus limited their applications for high concentrated wastewaters. In this study, asynchronous cross-linked triethylenetetramine modified sodium alginate (CFTS) was used as photocatalyst for the simultaneously catalytic degradation of Cr(VI) and metronidazole (MNZ). Experimental results suggested that asynchronous cross-linking and triethylenetetramine modification have dramatically enhanced the chemical stability as well as the adsorption and photocatalytic behavior of the material. The grafted amino functional groups and cross-linked Fe3+ ions can promote the rapid separation and transfer of electrons, thus reducing the recombination rate of photo-generated electron-hole pairs. The optimum removal rate of Cr (VI) has reached 99.5 % and MNZ can be completely removed within 20 and 30 min at pH 1.0 under UV light irradiation, respectively. The removal mechanism of Cr(VI) by CFTS is the synergistic effect of electrostatic adsorption and photocatalytic reduction, while photocatalytic oxidation dominated the degradation process of MNZ. Moreover, the removal efficiency can be enhanced in the binary solution of these two pollutants due to the utilization of photo generated electron-hole pairs, which provides new pathways in the treatment of complicated pharmaceutical and domestic sewage wastewaters.
  1. Sun J, Hou Y, Yu Z, Tu L, Yan Y, Qin S, et al., J. Hazard. Mater., 419, 126543 (2021)
  2. Liu J, Lu W, Wu H, Jin L, Hu B, Li L, et al., Mater. Sci. Semicond. Process, 56, 251 (2016)
  3. Wise JP, Young JL, Cai J, Cai LU, Environ. Int., 158 (2022)
  4. Yang Z, Zhang X, Jiang Z, Li Q, Huang P, Zheng C, et al., Sci. Total Environ., 773, 145654 (2021)
  5. Manoj S, RamyaPriya R, Elango L, Environ. Sci. Pollut. Res., 28(4), 4276 (2021)
  6. Asgari E, Esrafili A, Jafari AJ, Kalantary RR, Nourmoradi H, Farzadkia M, Process Saf. Environ. Protect., 128, 65 (2019)
  7. Neghia N, Kumar M, Burkhalov D, Chem. Eng. J., 359, 963 (2019)
  8. Ding K, Zhou X, Hadiatullah H, Lu Y, Zhao G, Jia S, et al., J. Hazard. Mater., 420, 126551 (2021)
  9. Rivera-Utrilla J, Prados-Joya G, Sánchez-Polo M, Ferro-García MA, Bautista-Toledo I, J. Hazard. Mater., 170(1), 298 (2009)
  10. Fang S, Zhang P, Gong J, Tang L, Zeng G, Song B, et al., Chem. Eng. J., 325, 123400 (2020)
  11. Jamshidifard S, Koushkbaghi S, Hosseini S, Rezaei S, Karamipour A, Jafarirad A, et al., J. Hazard. Mater., 368, 10 (2019)
  12. Zhang W, Qian L, Chen Y, Ouyang D, Han L, Shang X, et al., Chemosphere, 267, 129183 (2021)
  13. Li S, Wang C, Liu Y, Cai M, Wang Y, Zhang H, et al., Chem. Eng. J., 429, 132519 (2022)
  14. Chen Y, Li Y, Luo N, Shang W, Shi S, Li H, et al., Chem. Eng. J., 429, 132577 (2022)
  15. Tadesse SF, Kuo DH, Kebede WL, Wolde GS, Appl. Surf. Sci., 569, 151091 (2021)
  16. Song S, Wu K, Wu H, Guo J, Zhang L, J. Mater. Sci., 55, 4987 (2020)
  17. Tran ML, Nguyen CH, Fu CC, Juang RS, J. Environ. Manage., 252, 109611 (2019)
  18. Jiang Z, Ho SH, Wang X, Li Y, Wang C, Environ. Pollut., 290, 118087 (2021)
  19. Jin J, Sun J, Lv K, Huang X, Wang J, Liu J, et al., J. Mol. Liq., 334, 116087 (2021)
  20. Pooresmaeil M, Namazi H, Int. J. Biol. Macromol., 191, 108 (2021)
  21. Luo L, Luo L, Deng J, Chen T, Du G, Fan M, et al., Int. J. Hydrog. Energy, 46, 31927 (2021)
  22. Zhang W, Ou J, Wang B, Wang H, He Q, Song J, et al., J. Hazard. Mater., 418, 126358 (2021)
  23. Wu S, Guo J, Wang Y, Huang C, Hu Y, J. Mater. Sci., 56, 13096 (2021)
  24. Wang J, Guo M, Luo Y, Shao D, Ge S, Cai L, et al., J. Environ. Manage., 289, 112506 (2021)
  25. Feng Y, Wang H, Xu J, Du X, Cheng X, Du Z, et al., J. Hazard. Mater., 416, 125777 (2021)
  26. Li D, Zhang P, Yang Y, Huang Y, Li T, Yang J, J. Radioanal. Nucl. Chem., 327, 1131 (2021)
  27. Nawaz M, Khan AA, Hussain A, Jang J, Jung HY, Lee DS, Chemosphere, 261, 127702 (2020)
  28. Jin Q, Xie G, Cai X, Hu X, Wang H, Qiu G, et al., RSC. Adv., 10, 6121 (2020)
  29. Dong Y, Dong W, Cao Y, Han Z, Ding Z, Catal. Today, 175(1), 346 (2011)
  30. Li G, Zhang G, Sun R, Wong CP, J. Mater. Sci., 52, 8538 (2017)
  31. Ciocoiu ON, Staikos G, Vasile C, Carbohydr. Polym., 184, 118 (2018)
  32. Salomonsen T, Jensen HM, Larsen FH, Steuernagel S, Engelsen SB, Carbohydr. Res., 344(15), 2014 (2009)
  33. Lin C, Luo W, Luo T, Zhou Q, Li H, Jing L, J. Clean Prod., 196, 626 (2018)
  34. Ghanbarian M, Nabizadeh R, Nasseri S, Shemirani F, Mahvi AH, Beyki MH, et al., Int. J. Biol. Macromol., 104, 465 (2017)
  35. Azalok KA, Oladipo AA, Gazi M, Chemosphere, 268, 128844 (2021)
  36. Yang CC, Dao KC, Lin YS, Cheng TY, Chen KF, Tsai YP, Water, 13(16), 2291 (2021)
  37. Sin JC, Lam SM, Zeng H, Lin H, Li H, Tham KO, et al., Appl. Surf. Sci., 559, 149966 (2021)
  38. Naimi-Joubani M, Shirzad-Siboni M, Yang JK, Gholami M, Farzadkia M, J. Ind. Eng. Chem., 22, 317 (2015)
  39. Ibrahim I, Kaltzoglou A, Athanasekou C, Katsaros F, Devlin E, Kontos AG, et al., Chem. Eng. J., 381, 122730 (2020)
  40. Hu X, Zhao Y, Wang H, Cai X, Hu X, Tang C, et al., J. Chem. Technol. Biotechnol., 93, 2226 (2018)
  41. Sanad MMS, Abdel-Aal EA, Osman HM, Kandil AT, Int. J. Environ. Sci. Technol., 15, 2459 (2018)
  42. Raja A, Son N, Kang M, Sep. Purif. Technol., 281, 119872 (2022)
  43. Amouhadi E, Aliyan H, Aghaei H, Fazaeli R, Richeson D, Mater. Sci. Semicond. Process, 143, 106560 (2022)
  44. Kakavandi B, Dehghanifard E, Gholami P, Noorisepehr M, MirzaHedayat B, Appl. Surf. Sci., 570, 151145 (2021)
  45. Lv T, Li B, J. Polym. Environ., 29, 1576 (2021)
  46. Sanaei L, Tahmasebpoor M, Mater. Chem. Phys., 259, 124009 (2021)
  47. Li Y, Wang Z, Wang X, Yan B, Peng Y, Ran R, Carbohydr. Polym., 269, 118269 (2021)
  48. Gao X, Liu J, Li M, Guo C, Long H, Zhang Y, et al., Chem. Eng. J., 385, 123897 (2020)
  49. Guo C, Wu S, Gao X, Li M, Long H, Int. J. Biol. Macromol., 189, 910 (2021)
  50. Liu H, Ye M, Dong X, Ren Z, Long S, Lichtfouse E, J. Water. Process. Eng., 44, 102428 (2021)
  51. Hao D, Shen Q, Liu J, Wei L, Bibi R, Fu B, et al., Int. J. Biol. Macromol., 141, 1111 (2019)
  52. Wang F, Liao Y, Li T, Xia L, Sep. Purif. Technol., 299, 121707 (2022)
  53. Wang G, Bi W, Zhang Q, Dong X, Zhang X, J. Hazard. Mater., 426, 127821 (2022)
  54. Yang H, Zhang JF, Dai K, Chin. J. Catal., 43(2), 255 (2022)
  55. Zhu D, Zhou Q, Appl. Catal. B: Environ., 281, 119747 (2021)
  56. Gao S, Zhang P, Huang G, Chen Q, Bi J, Wu L, Chemsuschem, 14, 3850 (2021)
  57. He S, Yin R, Chen Y, Lai T, Guo W, Zeng L, et al., Chem. Eng. J., 423, 130172 (2021)
  58. Gao X, Zhang Y, Zhao Y, Carbohydr. Polym., 200, 297 (2018)
  59. Gao X, Li M, Zhao Y, Zhang Y, Chem. Eng. J., 378, 122096 (2019)
  60. Ocin´ski D, Sobala IJ, Balawejder EK, Environ. Sci. Pollut. Res., 23, 24527 (2016)
  61. Zhang G, Chen S, Yang Y, Liu Y, Lei L, Liu X, et al., Environ. Res., 202, 111661 (2021)
  62. Li Q, Xu H, Zhou G, Cheng F, Wang M, Zhang J, et al., Sep. Purif. Technol., 272, 118928 (2021)
  63. Cui Z, Zhang L, Wang Y, He W, Appl. Surf. Sci., 584, 152655 (2022)
  64. Ding C, Fu K, Pan Y, Liu J, Deng H, Shi J, Catalysts, 10(9), 1097 (2020)
  65. Wang X, Wang A, Lu M, Ma J, Chem. Eng. J., 337, 372 (2018)
  66. Kim D, Lee D, Satoca DM, Kim K, Lee W, Choi W, J. Hazard. Mater., 372, 121 (2019)
  67. Zhang W, Liu F, Sun Y, Zhang J, Hao Z, Appl. Catal. B: Environ., 259, 118046 (2019)
  68. Wang Q, Cai Z, Huang L, Pan Y, Quan X, Puma GL, Chem. Eng. J., 376, 119566 (2019)