화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Journal of Industrial and Engineering Chemistry, Vol.116, 310-320, December, 2022
DOI10.1016/j.jiec.2022.09.021  Export Citation
Mxene structure: A key parameter in corrosion barrier performance of organic coatings
Ziyang Zhou1, 2, Sepideh Pourhashem1, 3, Zhengquan Wang1, 2, Jiawen Sun1, 2, Xiaohong Ji1, 3, Xiaofan Zhai1, 3, Jizhou Duan1, 3, †, and Baorong Hou1, 3
  • 1Key Laboratory of Marine Environmental Corrosion and Bio-fouling, Institute of Oceanology, Chinese Academy of Sciences, 7 Nanhai Road, Qingdao 266071, China
  • 2University of Chinese Academy of Sciences, 19 (Jia) Yuquan Road, Beijing 100049, China
  • 3Open Studio for Marine Corrosion and Protection, Pilot National Laboratory for Marine Science and Technology (Qingdao), 1 Wenhai Road, Qingdao 266237, China
E-mail:
In this research, the effects of fresh and oxidized MXene on the surface, adhesion, and corrosion-resistant properties of waterborne epoxy coatings are considered. The oxidized MXene is prepared through storage of fresh MXene nanosheets in an open vial for 1 month. The results confirm that the waterborne epoxy coating loaded with silane functionalized fresh MXene nanosheets (epoxy/F-MXene) has significantly higher barrier performance and anti-corrosion behavior than the sample modified with silane functionalized oxidized MXene nanosheets (epoxy/F-O-MXene). Indeed, the F-MXene nanosheets (with defectfree and large two dimensional morphology) are able to effectively inhibit the path of corrosive media as well as increment the epoxy matrix compactness compared to the F-O-MXene (with broken nanosheet morphology composed of TiO2 nanoparticles) due to rapid oxidation of the MXene nanosheets in the environment. Besides, the epoxy/F-MXene nanocomposite coating has slightly higher water contact angle and adhesion strength to the metallic substrate compared to the epoxy/F-O-MXene. The results of this research clearly reveal the importance of preventing MXene oxidation before application as nanofiller in the polymer coatings.
Keywords:Nanocomposites;Layered structures;Barrier properties;Surface properties;Oxidation Stability
  1. Karahan HE, Goh K, Zhang CF, Yang E, Yildirim C, Chuah CY, et al., Adv. Mater., 32, 1906697 (2020)
  2. Naguib M, Gogotsi Y, Acc. Chem. Res., 48, 128 (2015)
  3. Naguib M, Mashtalir O, Carle J, Presser V, Lu J, Hultman L, et al., ACS Nano, 6, 1322 (2012)
  4. Rasool K, Helal M, Ali A, Ren CE, Gogotsi Y, Mahmoud KA, ACS Nano, 10, 3674 (2016)
  5. Urbankowski P, Anasori B, Makaryan T, Er DQ, Kota S, Walsh PL, et al., Nanoscale, 8, 11385 (2016)
  6. Anasori B, Lukatskaya MR, Gogotsi Y, Nat. Rev. Mater., 2, 1 (2017)
  7. Zhang CFJ, Pinilla S, McEyoy N, Cullen CP, Anasori B, Long E, et al., Chem. Mater., 29, 4848 (2017)
  8. Zhou J, Zha X, Zhou X, Chen F, Gao G, Wang S, et al., ACS Nano, 11, 3841 (2017)
  9. Habib T, Zhao XF, Shah SA, Chen YX, Sun WM, An H, et al., npj 2D Mater. Appl., 3, 1 (2019)
  10. Hantanasirisakul K, Zhao MQ, Urbankowski P, Halim J, Anasori B, Kota S, et al., Adv. Electron. Mater., 2, 1600050 (2016)
  11. Li XC, Qian YH, Liu T, Cao FT, Zang Z, Sun XL, et al., J. Mater. Sci., 53, 11078 (2018)
  12. Lin H, Wang YW, Gao SS, Chen Y, Shi JL, Adv. Mater., 32, 1703284 (2020)
  13. Zhang CF, Kim SJ, Ghidiu M, Zhao MQ, Barsoum MW, Nicolosi V, et al., Adv. Funct. Mater., 26, 4143 (2016)
  14. Wang DZ, Lin Y, Hu DW, Jiang PK, Huang XY, Compos. Pt. A-Appl. Sci. Manuf., 130, 105754 (2020)
  15. Huang KL, Li CH, Li HZ, Ren GM, Wang L, Wang WT, et al., Nano Mater., 3, 9581 (2020)
  16. Zha XJ, Zhao X, Pu JH, Tang LS, Ke K, Bao RY, et al., Mater. Interfaces, 11, 36589 (2019)
  17. Su TM, Ma XH, Tong JH, Ji HB, Qin ZZ, Wu ZL, J. Mater. Chem. A, 10, 10265 (2022)
  18. Shahzad F, Iqbal A, Zaidi SA, Hwang SW, Koo CM, J. Ind. Eng. Chem., 79, 338 (2019)
  19. Zhao B, Hamidinejad M, Wang S, Bai PW, Che RC, Zhang R, et al., J. Mater. Chem. A, 9, 8896 (2021)
  20. Prasad C, Yang XF, Liu QQ, Tang H, Rammohan A, Zulfiqar S, et al., J. Ind. Eng. Chem., 85, 1 (2020)
  21. Cao Y, Zeng ZH, Huang DY, Chen Y, Zhang L, Sheng XX, Nano Res, 15, 8524 (2022)
  22. Huang HW, Sheng XX, Tian YQ, Zhang L, Chen Y, Zhang XY, Ind. Eng. Chem. Res., 59, 15424 (2020)
  23. Yan H, Cai M, Wang JC, Zhang L, Li H, Li W, et al., Appl. Surf. Sci., 536, 147974 (2021)
  24. Yan H, Li W, Li H, Fan XQ, Zhu MH, Prog. Org. Coat., 135, 156 (2019)
  25. Sheng XX, Li SH, Huang HW, Zhao YF, Chen Y, Zhang L, et al., J. Mater. Sci., 56, 4212 (2021)
  26. Lipatov A, Alhabeb M, Lukatskaya MR, Boson A, Gogotsi Y, Sinitskii A, Adv. Electron. Mater., 2, 1600255 (2016)
  27. Mashtalir O, Cook KM, Mochalin VN, Crowe M, Barsoum MW, Gogotsi Y, J. Mater. Chem. A, 2, 14334 (2014)
  28. Iqbal A, Hong J, Ko TY, Koo CM, Nano Convergence, 8, 1 (2021)
  29. Chen DW, Zou YQ, Wang SY, Mater. Today Energy, 12, 250 (2019)
  30. Ji JJ, Zhao LF, Shen YF, Liu SQ, Zhang YJ, Flatchem, 17 (2019)
  31. Zhao HR, Ding JH, Zhou M, Yu HB, ACS Appl. Nano Mater., 4, 3075 (2021)
  32. He X, Wu J, Li S, Chen Y, Zhang L, Sheng X, Prog. Org. Coat., 171, 107042 (2022)
  33. He XL, Li SH, Wu JX, Chen Y, Zhang L, Sheng XX, Ind. Eng. Chem. Res. (2022)
  34. He XL, Li SH, Shen RBA, Ma YQ, Zhang L, Sheng XX, et al., Adv. Compos. Hybrid Mater, 1 (2022)
  35. Pourhashem S, Saba F, Duan JZ, Rashidi A, Guan F, Nezhad EG, et al., J. Ind. Eng. Chem., 88, 29 (2020)
  36. Zhou Z, Ji X, Pourhashem S, Duan J, Hou B, Compos. Pt. A-Appl. Sci. Manuf., 149, 106568 (2021)
  37. Ma YQ, Huang HW, Zhou HD, Graham M, Smith J, Sheng XX, et al., J. Mater. Sci. Technol., 95, 95 (2021)
  38. Wang Q, Wang W, Ji XH, Hao XP, Ma CC, Hao W, et al., Mater. Interfaces, 13, 3139 (2021)
  39. Liu TF, Li W, Zhang CY, Wang W, Dou WW, Chen SG, J. Ind. Eng. Chem., 97, 560 (2021)
  40. Yan H, Cai M, Li W, Fan XQ, Zhu MH, J. Mater. Sci. Technol., 54, 144 (2020)
  41. Nandiyanto ABD, Oktiani R, Ragadhita R, Indonesian J. Sci. Technol., 4(1), 97 (2019)
  42. Shi F, Sun J, Wang J, Liu M, Nunes SP, Front. Chem., 8, 58 (2020)
  43. Riazi H, Anayee M, Hantanasirisakul K, Shamsabadi AA, Anasori B, Gogotsi Y, et al., Adv. Mater. Interfaces, 7, 1902008 (2020)
  44. Xue Q, Pei Z, Huang Y, Zhu M, Tang Z, Li H, et al., J. Mater. Chem. A, 5, 20818 (2017)
  45. Meroni D, Presti LL, Di Liberto G, Ceotto M, Acres RG, Prince KC, et al., J. Phys. Chem. C, 121, 430 (2017)
  46. Zhang J, Kong N, Hegh D, Usman K, Razal JM, ACS Appl. Mater. Interfaces (2020)
  47. Ma Z, Zhou X, Deng W, Lei DA, Liu Z, ACS Appl. Mater. Interfaces, 10, 3634 (2018)
  48. Li W, Li X, Chang W, Wu J, Liu P, Wang J, et al., Nano Res., 13, 9 (2020)
  49. Habib T, Zhao X, Shah SA, Chen Y, Green MJ, npj 2D Mater. Appl., 3, 8 (2019)
  50. Natu V, Benchakar M, Canaff C, Habrioux A, Celerier S, Barsoum MW, Matter, 4, 1224 (2021)
  51. Wu Y, Yang JQ, Lin YC, Xu J, Molecules, 24, 3657 (2019)
  52. Yan XB, Xu T, Chen G, Yang SR, Liu HW, Xue QJ, J. Phys. D-Appl. Phys., 37, 907 (2004)
  53. M.G. A, P.X. B, T.A. A,, J. Nucl. Mater., 462, 100 (2015)
  54. Bai Y, Li Z, Cheng B, Zhang M, Su K, RSC Adv., 7, 21758 (2017)
  55. Wang XM, Wang JW, Li Q, Li SQ, J. Macromol. Sci.-Phys., 52, 751 (2013)
  56. Han MK, Yin XW, Wu H, Hou ZX, Song CQ, Li XL, et al., Mater. Interfaces, 8, 21011 (2016)
  57. Liu L, Ying GB, Wen D, Zhang KC, Hu C, Zheng YT, et al., Mater. Des., 197, 109276 (2021)
  58. Aghili M, Yazdi MK, Ranjbar Z, Jafari SH, Corrosion Sci., 179, 109143 (2021)
  59. Parhizkar N, Shahrabi T, Ramezanzadeh B, Corrosion Sci., 123, 55 (2017)
  60. Sari MG, Abdolmaleki M, Rostami M, Ramezanzadeh B, Corrosion Sci., 173, 108799 (2020)
  61. Ramezanzadeh B, Ahmadi A, Mandavian M, Corrosion Sci., 109, 182 (2016)