화학공학소재연구정보센터
Journal of Industrial and Engineering Chemistry, Vol.115, 554-560, November, 2022
Effect of heat treatment on the electrochemical performance of V2O5∙nH2O as a cathode material for aqueous rechargeable zinc ion batteries
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The influence of heat treatment (100 ℃, 150 ℃, 200 ℃, 300 ℃, and 400 ℃) on the structure and the zinc ion storage performance of V2O5∙nH2O is explored. The results show that the interlayer water content, interlayer distance, and V4+ content in V2O5∙nH2O can be regulated by heat treatment. Electrochemical characterization demonstrates that the as-prepared vanadium pentoxide without heat treatment shows rather poor cycling stability (only 56 m Ah g-1 after 600 cycles at 0.5 A/g). After being heat treated in the temperature range of 100 to 200 ℃, the zinc ion storage performance of vanadium pentoxide can be enhanced dramatically. Particularly, the vanadium pentoxide after being heat-treated at 150 ℃ exhibits the best cycling stability (179 mA h g-1 after 600 cycles at 0.5 A/g), superior high-rate capability (117 mA h g-1 at 3.0 A/g), and faster electrochemical reaction kinetics. The results reported in this work could provide clues for regulating and optimizing the electrochemical performance of vanadium pentoxide as a cathode material for ZIBs.
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