화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Journal of Industrial and Engineering Chemistry, Vol.114, 391-401, October, 2022
DOI10.1016/j.jiec.2022.07.028  Export Citation
Simple scalable approach to advanced membrane module design and hydrogen separation performance using twelve replaceable palladium-coated Al2O3 hollow fibre membranes
Soomin Lim, Edoardo Magnone, Min Chang Shin, Jeong Won Kang1, Kwan-Young Lee1, Chang-Hun Jeong2, and Jung Hoon Park†
  • Department of Biochemical and Chemical Engineering, Dongguk University, Seoul 04620, Republic of Korea
  • 1Department of Chemical and Biological Engineering, Korea University, Seoul 02841, Republic of Korea
  • 2Hygenenergy Co., Ltd., Misa-daero, Hanam-si, Gyeonggi-do, Republic of Korea
E-mail:
A phase-inversion approach was used to manufacture Al2O3 hollow fibre supports, which were then sintered at 1723 K. The electroless plating technique is developed to prepare palladium-coated Al2O3 hollow fibre membranes for hydrogen separation. Three different scaling-up configurations were produced and tested: single membrane, membrane unit obtained by assembling three membranes, and advanced membrane module obtained by assembling twelve replaceable membranes. The hydrogen flux was investigated under vacuum and without vacuum using a feed gas of pure H2 (100%) and a binary feed gas mixture of H2 (80%) and CO2 (20%) at different feed gas pressures (100–800 kPa), feed gas rate (0.2–6. 0 L min-1), and temperature (673–723 K). The hydrogen flux increases from 0.2162 mol m-2 s-1 (feed gas pressure = 600 kPa, feed gas rate = 0.2 L min-1) to 0.4487 mol m-2 s-1 (feed gas pressure = 800 kPa, feed gas rate = 6.0 L min-1) under the binary gas mixture at 723 K by switching from a single to the advanced membrane module, while the hydrogen purity remains above 97.5% throughout the experiment. Some aspects about the scalability of palladium-coated Al2O3 hollow fibre membranes for hydrogen separation are discussed.
Keywords:Membrane module design;Hydrogen separation properties;Palladium coatings;Electroless plating process;Al2O3 hollow fibre supports
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