화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Journal of Industrial and Engineering Chemistry, Vol.113, 1-14, September, 2022
DOI10.1016/j.jiec.2022.05.029  Export Citation
Magnetic molecularly imprinted polymer photocatalysts: synthesis, applications and future perspective
Komal Poonia, Pankaj Raizada†, Archana Singh1, Narinder Verma2, Tansir Ahamad3, Saad M. Alshehri3, Aftab Aslam Parwaz Khan4, Pardeep Singh, and Chaudhery Mustansar Hussain5, †
  • School of Advanced Chemical Sciences, Shoolini University, Solan, (Himachal Pradesh) 173212, India
  • 1Advanced Materials and Processes Research Institute, Hoshangabad Road, Bhopal, (MP) 462026, India
  • 2Faculty of Business Management, Shoolini University, Solan 173212, India
  • 3Department of Chemistry, College of Science, King Saud University, Saudi Arabia
  • 4Center of Excellence for Advanced Materials Research, King Abdulaziz University, P. O. Box 80203, Jeddah 21589, Saudi Arabia
  • 5Department of Chemistry and Environmental Science, New Jersey Institute of Technology, Newark, NJ 07102, United States, USA
E-mail:,
Effective degradation of low-concentration pollutants is a critical challenge during the water purification process. The use of different chemicals can leave residue in samples that can impose potential ecotoxicological and adverse impacts on human health. Presently, Magnetic molecularly imprinted polymers (M-MIPs) have attracted much attention as the research material comprises a non-magnetic polymer and magnetic material for selective binding for target molecule and recoverability of catalyst via magnetism, respectively. This review explains the synergistic effect of adsorption with photocatalysis to understand their recognition mechanism and the possible interaction between the target molecule and MIPs. Then their common imprinting polymerization processes i.e., free radical polymerization and non-free radical polymerization are briefly discussed with their respective advantages and disadvantages. In addition, this review highlights the photocatalytic degradation mechanism of photocatalyst cum adsorbent is critically discussed by comparing it with non-imprinted polymers. Finally, the applications of M-MIPs in the removal or degradation of refractory pollutants, sensing, and recognition have also been delineated. This paper summarises progressive future challenges of the technology that need to be exploited for the preparation of the targeted catalyst.
Keywords:Molecularly imprinted polymer;photocatalyst;Magnetic separation;Synthetic strategy;Photocatalytic applications
  1. Adu AA, Neolaka YA, Riwu AAP, Iqbal M, Darmokoesoemo H, Kusuma HS, J. Mater. Res. Technol., 9(5), 11060 (2020)
  2. Afzali M, Mostafavi A, Shamspur T, Arab. J. Chem., 13(8), 6626 (2020)
  3. Anirudhan T, Christa J, Shainy F, React. Funct. Polym., 152, 104597 (2020)
  4. Ansari S, Trends Anal. Chem., 90, 89 (2017)
  5. Ansari S, Trends Anal. Chem., 93, 134 (2017)
  6. Ansari S, Karimi M, Talanta, 167, 470 (2017)
  7. Ansell RJ, Mosbach K, Analyst, 123(7), 1611 (1998)
  8. Arabi M, Ostovan A, Li J, Wang X, Zhang Z, Choo J, et al., Adv. Mater., 33(30), 2100543 (2021)
  9. Arabzadeh N, Mohammadi A, Darwish M, Abuzerr S, J. Chin. Chem. Soc., 66(5), 474 (2019)
  10. BelBruno JJ, Chem. Rev., 119(1), 94 (2018)
  11. Chandel N, Sharma K, Sudhaik A, Raizada P, Hosseini-Bandegharaei A, Thakur VK, et al., Arab. J. Chem., 13(2), 4324 (2020)
  12. Chang T, Yan X, Liu S, Liu Y, Food Anal. Methods, 10(12), 3980 (2017)
  13. Chen L, Li B, Anal. Methods, 4(9), 2613 (2012)
  14. Chen L, Xu S, Li J, Chem. Soc. Rev., 40(5), 2922 (2011)
  15. Chen MJ, Yang HL, Si YM, Tang Q, Chow CF, Gong CB, Photoresponsive Surface Molecularly Imprinted Polymers for the Detection of Profenofos in Tomato and Mangosteen. Frontiers in chemistry, 905, 2020.
  16. Chong MN, Jin B, Chow CW, Saint C, Water Res., 44(10), 2997 (2010)
  17. Cui Y, Ding L, Ding J, Trends Anal. Chem., 116514 (2022)
  18. de Escobar CC, Ruiz YPM, dos Santos JHZ, Ye L, Colloids Surf. A: Physicochem. Eng. Asp., 538, 729 (2018)
  19. Dutta V, Sharma S, Raizada P, Thakur VK, Khan AAP, Saini V, et al., J. Environ. Chem. Eng., 9(1), 105018 (2021)
  20. Duttaa KSV, Sharmaa S, Raizadaa P, Hosseini-Bandegharaeic A, Thakura P, Singh P, Recent advances in enhanced photocatalytic activity of bismuth oxyhalides for efficient photocatalysis of organic pollutants in water: a review, 2019.
  21. Fan JP, Xu XK, Xu R, Zhang XH, Zhu JH, Chem. Eng. J., 279, 567 (2015)
  22. Fang L, Miao Y, Wei D, Zhang Y, Zhou Y, Chemosphere, 262, 128032 (2021)
  23. Fang L, Tang K, Wei D, Zhang Y, Zhou Y, Environ. Technol., 1 (2021)
  24. Farooq S, Wu H, Nie J, Ahmad S, Muhammad I, Zeeshan M, et al., Sci. Total Environ., 804, 150293 (2022)
  25. Fiorenza R, Di Mauro A, Cantarella M, Iaria C, Scalisi EM, Brundo MV, et al., Chem. Eng. J., 379, 122309 (2020)
  26. Foroughirad S, Arabzadeh N, Mohammadi A, Khosravi A, J. Chin. Adv. Mat. Soc., 6(4), 706 (2018)
  27. Gao R, Su X, He X, Chen L, Zhang Y, Talanta, 83(3), 757 (2011)
  28. GracePavithra K, Jaikumar V, Kumar PS, SundarRajan P, J. Clean Prod., 228, 580 (2019)
  29. Guan G, Pan JH, Li Z, Chemosphere, 265, 129077 (2021)
  30. Gui R, Jin H, J. Photochem. Photobiol. C-Photochem. Rev.
  31. Guo J, Yu M, Wei X, Huang L, J. Chem. Eng. Data, 63(8), 3068 (2018)
  32. Guo M, Hu Y, Wang R, Yu H, Sun L, Environ. Res., 194, 110684 (2021)
  33. Han S, Yao A, Ding Y, Leng Q, Teng F, Anal. Bioanal. Chem., 413(21), 5409 (2021)
  34. Hasanah AN, Safitri N, Zulfa A, Neli N, Rahayu D, Molecules, 26(18), 5612 (2021)
  35. Hasija V, Kumar A, Sudhaik A, Raizada P, Singh P, Van Q Le, et al., Environ. Chem. Lett., 19(4), 2941 (2021)
  36. Hasija V, Nguyen VH, Kumar A, Raizada P, Krishnan V, Khan AAP, et al., J. Hazard. Mater., 413, 125324 (2021)
  37. He S, Zhang L, Bai S, Yang H, Cui Z, Zhang X, et al., Eur. Polym. J., 143, 110179 (2021)
  38. Huang C, Tu Z, Shen X, J. Hazard. Mater., 248, 379 (2013)
  39. Huang J, Tong J, Luo J, Zhu Y, Gu Y, Liu X, ACS Sustainable Chem. Eng., 6(8), 9760 (2018)
  40. Huang M, Zhou T, Wu X, Mao J, Chin. J. Chem. Eng., 23(10), 1698 (2015)
  41. Huang S, Xu J, Zheng J, Zhu F, Xie L, Ouyang G, Anal. Bioanal. Chem., 410(17), 3991 (2018)
  42. Huang Y, Wang P, Chen F, Zhou G, Song M, Liu X, et al., J. Photochem. Photobiol. A-Chem., 410, 113159 (2021)
  43. Huang YP, Liu ZS, Zheng C, Gao RY, Electrophoresis, 30(1), 155 (2009)
  44. Ji Y, Yin J, Xu Z, Zhao C, Huang H, Zhang H, et al., Anal. Bioanal. Chem., 395(4), 1125 (2009)
  45. Kalia S, Kango S, Kumar A, Haldorai Y, Kumari B, Kumar R, Colloid Polym. Sci., 292(9), 2025 (2014)
  46. Khan S, Wong A, Zanoni MVB, Sotomayor MDPT, Mater. Sci. Eng. C-Biomimetic Supramol. Syst., 103, 109825 (2019)
  47. Kong X, Gao R, He X, Chen L, Zhang Y, J. Chromatogr. A, 1245, 8 (2012)
  48. Kuhn J, Aylaz G, Sari E, Marco M, Yiu HH, Duman M, J. Hazard. Mater., 387, 121709 (2020)
  49. Lai C, Zhou X, Huang D, Zeng G, Cheng M, Qin L, et al., J. Taiwan Inst. Chem. Eng., 91, 517 (2018)
  50. Lanza F, Sellergren B, Chromatographia, 53(11), 599 (2001)
  51. Laskar N, Ghoshal D, Gupta S, Iran. Polym. J., 30(2), 121 (2021)
  52. Li F, Gao J, Li X, Li Y, He X, Chen L, et al., J. Chromatogr. A, 1602, 168 (2019)
  53. Li N, Yang H, J. Hazard. Mater., 403, 123643 (2021)
  54. Li S, Wu X, Zhang Q, Li P, Microchimica Acta, 183(4), 1433 (2016)
  55. Li X, Wang J, Li M, Jin Y, Gu Z, Liu C, et al., Chin. Chem. Lett., 29(3), 527 (2018)
  56. Li X, Yang B, Xiao K, Duan H, Wan J, Zhao H, Water Res., 203, 117541 (2021)
  57. Lima EC, Adebayo MA, Machado FM, Springer, 33 (2015)
  58. Liu C, Chen M, Li H, Shi Q, Feng Y, Zhang B, Crystal Growth Des. (2022)
  59. Liu G, Yang X, Li T, She Y, Wang S, Wang J, et al., Mater. Lett., 160, 472 (2015)
  60. Liu H, Guo W, Li Y, He S, He C, J. Environ. Chem. Eng., 6(1), 59 (2018)
  61. Liu X, Yu D, Yu Y, Ji S, Appl. Surf. Sci., 320, 138 (2014)
  62. Lu YC, Mao JH, Zhang W, Wang C, Cao M, Wang XD, et al., Chemosphere, 238, 124640 (2020)
  63. Lu Z, Chen F, He M, Song M, Ma Z, Shi W, et al., Chem. Eng. J., 249, 15 (2014)
  64. Luo J, Gao Y, Tan K, Wei W, Liu X, ACS Sustainable Chem. Eng., 4(6), 3316 (2016)
  65. Luo Y, Lu Z, Jiang Y, Wang D, Yang L, Huo P, et al., Chem. Eng. J., 240, 244 (2014)
  66. Madikizela LM, Tavengwa NT, Tutu H, Chimuka L, Trends Environ. Anal. Chem., 17, 14 (2018)
  67. Maksoud MA, Elgarahy AM, Farrell C, Ala’a H, Rooney DW, Osman AI, Coord. Chem. Rev., 403, 213096 (2020)
  68. Moein MM, Abdel-Rehim A, Abdel-Rehim M, Molecules, 24(16), 2889 (2019)
  69. Orowitz TE, Sombo PPAAA, Rahayu D, Hasanah AN, Molecules, 25(14), 3256 (2020)
  70. Pan J, Chen W, Ma Y, Pan G, Chem. Soc. Rev., 47(15), 5574 (2018)
  71. Parlapiano M, Akyol C, Foglia A, Pisani M, Astolfi P, Eusebi AL, et al., J. Environ. Chem. Eng., 9(1), 105051 (2021)
  72. Piletsky S, Canfarotta F, Poma A, Bossi AM, Piletsky S, Trends Biotechnol., 38(4), 368 (2020)
  73. Pratiwi R, Megantara S, Rahayu D, Pitaloka I, Hasanah AN, J. Young Pharmacists, 11(1), 12 (2019)
  74. Qin L, Liu WF, Liu XG, Yang YZ, Zhang LA, New Carbon Mater., 35(5), 459 (2020)
  75. Renkecz T, László K, Horváth V, Molecular Imprinting, 2(1), 1 (2014)
  76. Sajini T, Mathew B, Talanta Open, 4, 100072 (2021)
  77. Schneider J, Matsuoka M, Takeuchi M, Zhang J, Horiuchi Y, Anpo M, et al., Chem. Rev., 114(19), 9919 (2014)
  78. Shen X, Xu C, Ye L, Ind. Eng. Chem. Res., 52(39), 13890 (2013)
  79. Singh M, Singh S, Singh SP, Patel SS, Trends Environ. Anal. Chem., 27, e00092 (2020)
  80. Singh P, Sharma K, Hasija V, Sharma V, Sharma S, Raizada P, et al., Mater. Today Chem., 14, 100186 (2019)
  81. Soni V, Raizada P, Kumar A, Hasija V, Singal S, Singh P, et al., Environ. Chem. Lett., 19(2), 1065 (2021)
  82. Speltini A, Scalabrini A, Maraschi F, Sturini M, Profumo A, Anal. Chim. Acta, 974, 1 (2017)
  83. Sun L, Li J, Li X, Liu C, Wang H, Huo P, et al., J. Colloid Interface Sci., 552, 271 (2019)
  84. Tang H, Zhu L, Yu C, Shen X, Sep. Purif. Technol., 95, 165 (2012)
  85. Thévenot J, Oliveira H, Sandre O, Lecommandoux S, Chem. Soc. Rev., 42(17), 7099 (2013)
  86. Tri NLM, Kim J, Giang BL, Al Tahtamouni T, Huong PT, Lee C, et al., J. Ind. Eng. Chem., 80, 597 (2019)
  87. Vaihinger D, Landfester K, Kräuter I, Brunner H, Tovar GE, Macromol. Chem. Phys., 203(13), 1965 (2002)
  88. Vasconcelos I, da Silva PHR, Dias DRD, de Freitas Marques MB, da Nova Mussel W, Pedrosa TA, et al., Mater. Sci. Eng. C-Biomimetic Supramol. Syst., 116, 111191 (2020)
  89. Wang R, Pan J, Qin M, Guo T, Eur. Polym. J., 110, 1 (2019)
  90. Wang Z, Qiu T, Guo L, Ye J, He L, Li X, Chem. Eng. J., 357, 348 (2019)
  91. Wang Z, Zhang Z, Yan R, Fu X, Wang G, Wang Y, et al., React. Funct. Polym., 164, 104911 (2021)
  92. Wei D, Li S, Fang L, Zhang Y, Environ. Sci. Pollut. Res., 25(7), 6729 (2018)
  93. Wulff G, Angew. Chem.-Int. Edit., 11(4), 341 (1972)
  94. Xu C, Shen X, Ye L, J. Mater. Chem., 22(15), 7427 (2012)
  95. Yin X, Long J, Xi Y, Luo X, ACS Sustainable Chem. Eng., 5(3), 2090 (2017)
  96. Yoshimatsu K, Reimhult K, Krozer A, Mosbach K, Sode K, Ye L, Anal. Chim. Acta, 584(1), 112 (2007)
  97. Zhang C, Chen H, Ma M, Yang Z, J. Mol. Catal. A-Chem., 402, 10 (2015)
  98. Zhang P, Mo Z, Han L, Wang Y, Zhao G, Zhang C, et al., J. Mol. Catal. A-Chem., 402, 17 (2015)
  99. Zhang Y, Liu R, Hu Y, Li G, Anal. Chem., 81(3), 967 (2009)
  100. Zhou T, Ding L, Che G, Jiang W, Sang L, Trends Anal. Chem., 114, 11 (2019)
  101. Zhu W, Zhou Y, Liu S, Luo M, Du J, Fan J, et al., Food Chem., 348, 129126 (2021)
  102. Dutta V, Sharma S, Raizada P, Hosseini-Bandegharaei A, Gupta VK, Singh P, J. Saudi Chem. Soc., 23(8), 1119 (2019)
  103. Xu C, Uddin KMA, Shen X, Jayawardena HSN, Yan M, Ye L, ACS Appl. Mater. Interfaces, 5(11), 5208 (2013)