화학공학소재연구정보센터
Journal of Industrial and Engineering Chemistry, Vol.112, 348-357, August, 2022
Anti-fouling nanofiltration membranes based on macromolecule crosslinked polyvinyl alcohol
E-mail:
Nanofiltration membranes with excellent anti-fouling properties were fabricated through a green surface crosslink method. Poly (styrene-maleic anhydride) (SMA) blended polyethersulfone (PES) membrane was used as a support. The SMA in the PES support served as a macromolecular crosslinker. After coating of polyvinyl alcohol (PVA) on the surface of the SMA-PES support, a PVA selective layer with gradient crosslinked structure was formed, through the esterification between the anhydride groups in SMA and the hydroxyl groups in PVA. This process adopts a full-water fabrication strategy without secondary pollution. The gradiently cross-linked PVA/SMA-PES membrane, with molecular weight cut-off (MWCO) about 600 Da and permeance around 10-12 L/(m2∙h∙bar), exhibited good dye/salts separation performance. In the filtration of a mixed solution of Congo Red (CR) and calcium chloride (CaCl2), the membrane rejected 98% CR and only had 10% rejection of CaCl2. In addition, this membrane processed an excellent antifouling property. In the BSA fouling test, the pure water flux recovery ratio (FRR) was 99%. It is expected that the PVA/SMA-PES membrane can be used in organic desalination.
  1. Košutic K, Furac L, Sipos L, Kunst B, Sep. Purif. Technol., 42, 137 (2005)
  2. Rahimpour A, Jahanshahi M, Mortazavian N, Madaeni SS, Mansourpanah Y, Appl. Surf. Sci., 256, 1657 (2010)
  3. Zhao S, Wang Z, J. Membr. Sci., 524, 214 (2017)
  4. Agboola O, Sunday O, Isaac, Fayomi, Sadiku R, Popoola P, Adeniyi P, Alaba, Adegbola AT, Materials Today Proc., 43, 3365 (2021)
  5. Bojnourd FM, Pakizeh M, Sep. Purif. Technol., 192, 5 (2018)
  6. Jahanshahi M, Rahimpour A, Mortazavian N, Iran. Polym. J., 21, 375 (2012)
  7. Zhang YQ, Guo J, Han G, Bai YQ, Ge QC, Ma J, et al., Sci. Adv., 7 (2021)
  8. Abdullah N, Yusof N, Lau WJ, Jaafar J, Is AF, J. Ind. Eng. Chem., 76, 17 (2019)
  9. Wang W, Sun J, Zhang Y, Zhang Y, Hong G, Moutloali RM, et al., Sci. Total Environ., 817, 153051 (2022)
  10. Zhang Y, Ma J, Shao L, J. Mater. Chem. A, 8, 5078 (2020)
  11. Mohammad AW, Teow YH, Ang WL, Chung YT, Oatley-Radcliffe DL, Hilal N, Desalination, 356, 226 (2015)
  12. Oatley-Radcliffe DL, Walters M, Ainscough TJ, Williams PM, Mohammad AW, Hilal N, J. Water Process Eng., 19, 164 (2017)
  13. Huang JH, Cheng XQ, Wu YD, Zhang YQ, Li SW, Lau CH, et al., Adv. Compos. Hybrid Mater., 4, 1092 (2021)
  14. Zhang F, Fan JB, Wang S, Angew. Chem.-Int. Edit., 59(1856), 21840 (2020)
  15. Ji C, Zhai Z, Jiang C, Hu P, Zhao S, Xue S, et al., Desalination, 500 (2021)
  16. An Q, Li F, Ji Y, Chen H, J. Membr. Sci., 367, 158 (2011)
  17. Tan SCZ, Peng X, Zhang L, Ga C, Science, (2018).
  18. Liu M, Chen Q, Wang L, Yu S, Gao C, Desalination, 367, 11 (2015)
  19. Zhang Q, Zhang C, Xu J, Nie Y, Li S, Zhang S, Desalination, 379, 42 (2016)
  20. Zhu X, Cheng X, Luo X, Liu Y, Xu D, Tang X, et al., Environ. Sci. Technol., 54, 6365 (2020)
  21. Jiang S, Liu S, Feng W, J. Mech. Behav. Biomed. Mater., 4, 1228 (2011)
  22. Kamoun EA, Loutfy SA, Hussein Y, Kenawy ES, Int. J. Biol. Macromol., 187, 755 (2021)
  23. Pourjafar S, Rahimpour A, Jahanshahi M, J. Ind. Eng. Chem., 18, 1398 (2012)
  24. Bagheripour E, Moghadassi AR, Parvizian F, Hosseini SM, Van der Bruggen B, Chem. Eng. Res. Des., 144, 418 (2019)
  25. Barona GN, Choi M, Jung B, J. Colloid Interface Sci., 386, 189 (2012)
  26. Liu M, Zhou C, Dong B, Wu Z, Wang L, Yu S, et al., J. Membr. Sci., 463, 173 (2014)
  27. Peng F, Jiang Z, Hoek EMV, J. Membr. Sci., 368, 26 (2011)
  28. Aguilar-Sanchez A, Jalvo B, Mautner A, Rissanen V, Kontturi KS, Abdelhamid HN, et al., RSC Adv., 11, 6859 (2021)
  29. Guo M, Wang S, Gu K, Song X, Zhou Y, Gao C, J. Membr. Sci., 569, 83 (2019)
  30. Dorr JM, Scheidelaar S, Koorengevel MC, Dominguez JJ, Schafer M, van Walree CA, et al., Eur. Biophys. J. Biophys. Lett., 45, 3 (2016)
  31. Bai L, Liu Y, Ding A, Ren N, Li G, Liang H, Chem. Eng. J., 358, 1519 (2019)
  32. Goh K, Setiawan L, Wei L, Si R, Fane AG, Wang R, et al., J. Membr. Sci., 474, 244 (2015)
  33. Ren J, Li Z, Wong FS, J. Membr. Sci., 279, 558 (2006)
  34. Zhang X, Tian J, Ren Z, Shi W, Zhang Z, Xu Y, et al., J. Membr. Sci., 520, 529 (2016)
  35. Vatanpour V, Madaeni SS, Moradian R, Zinadini S, Astinchap B, J. Membr. Sci., 375, 284 (2011)
  36. Zhu LP, Zhang XX, Xu L, Du CH, Zhu BK, Xu YY, Colloids Surf. B: Biointerfaces, 57, 189 (2007)
  37. Mahdavi H, Ardeshiri F, J. Iran. Chem. Soc., 13, 873 (2016)
  38. Bian L, Shen C, Song C, Zhang S, Cui Z, Yan F, et al., J. Membr. Sci., 620 (2021)
  39. Shen C, Yang J, Cui Z, Qin S, Qin Q, J. Taiwan Institute Chem. Eng., 112, 193 (2020)
  40. Luo S, Qiao X, Wang QY, Zhang YF, Fu P, Lin ZD, et al., J. Mater. Sci., 54, 5961 (2019)
  41. Gui W, Yang Y, Zhu X, J. Appl. Polym. Sci., 133 (2016)
  42. Sahin A, Electrochim. Acta, 271, 127 (2018)
  43. Zhu LP, Yi Z, Liu F, Wei XZ, Zhu BK, Xu YY, Eur. Polym. J., 44, 1907 (2008)
  44. Jin J, Du X, Yu J, Qin S, He M, Zhang K, et al., J. Membr. Sci., 611 (2020)
  45. Zhu X, Yang Z, Gan Z, Cheng X, Tang X, Luo X, et al., J. Membr. Sci., 614 (2020)
  46. Babu J, Murthy ZVP, Sep. Purif. Technol., 183, 66 (2017)
  47. Ahmad AL, Yusuf NM, Ooi BS, Desalination, 287, 35 (2012)
  48. Tesha JM, Dlamini DS, Cui Z, Li J, Mater. Today Commun., 21 (2019)
  49. Tesha JM, Dlamini DS, Qaseem S, Cui Z, Li J, J. Environ. Chem. Eng., 8 (2020)
  50. Kumar A, Ryparová P, Hosseinpourpia R, Adamopoulos S, Prošek Z, Zigon J, et al., Chem. Eng. J., 360, 788 (2019)
  51. Sakarkar S, Muthukumaran S, Jegatheesan V, Chemosphere, 257, 127144 (2020)
  52. Januário EFD, Vidovix TB, Calsavara MA, Bergamasco R, Vieira AMS, Chem. Eng. Process., 170 (2022)
  53. Li X, Chen Y, Hu X, Zhang Y, Hu L, J. Membr. Sci., 471, 118 (2014)
  54. Amiri S, Asghari A, Vatanpour V, Rajabi M, Sep. Purif. Technol., 250 (2020)