화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Applied Chemistry for Engineering, Vol.33, No.3, 258-271, June, 2022
DOI10.14478/ace.2022.1030    Full-Text PDF Export Citation
Newer Insights on Ferrate(VI) Reactions with Various Water Pollutants: A Review
Levia Lalthazuala, Lalhmunsiama1, Chhakchhuak Vanlalhmingmawia, Diwakar Tiwari†, Suk Soon Choi2, and Seung-Mok Lee3, †
  • Department of Chemistry, Mizoram University, Aizawl-796004, India
  • 1Department of Industrial Chemistry, Mizoram University, Aizawl-796004, India
  • 2Department of Biological and Environmental Engineering, Semyung University, Jecheon 27136, Republic of Korea
  • 3Department of Environmental Engineering, Catholic Kwandong University, Gangneung 25601, Republic of Korea
E-mail:,
Ferrate (VI) [Fe(VI)] has multi-functional features, which include potential oxidant, coagulant, and disinfectant. Because of these distinctive properties, numerous studies on the synthesis of ferrate (VI) and its possible applications in a wide research areas have been investigated. This review highlights the recent development made on different synthesis methods for ferrate including wet chemical, electrochemical, and thermal methods. The recent advancements achieved in ferrate (VI) oxidation and the synergistic effect of the oxidative properties of ferrate (VI) in the presence of various compounds or materials are also included. Moreover, this review discusses the applications of ferrate (VI) for degrading various types of water pollutants and its reaction mechanism. The optimized experimental conditions and interaction mechanisms of ferrate (VI) with micro-pollutants, dyes, and other organic compounds are also elaborated upon to provide greater insight for future studies. Lastly, the limitations and prospects of the ferrate use in the treatment of polluted water are described.
Keywords:High-valent iron (Fe(VI));Mineralization;Micro-pollutants;Mechanism;Synthesis of high purity Fe(VI);Insights of reactions
  1. Satapute P, Paidi MK, Kurjogi M, Jogaiah S, Environ. Pollut., 251, 555 (2019)
  2. Chen J, Xu X, Zeng X, Feng M, Qu R, Wang Z, Nesnas N, Sharma VK, Water Res., 143, 1 (2018)
  3. Bhavya G, Belorkar SA, Mythili R, Geetha N, Shetty HS, Udikeri SS, Jogaiah S, Chemosphere, 275, 1 (2021)
  4. Gago-Ferrero P, Gros M, Ahrens L, Wiberg K, Sci. Total Environ., 601-602, 1289 (2017)
  5. Klatte S, Schaefer HC, Hempel M, Sustain. Chem. Pharm., 5, 61 (2017)
  6. Talaiekhozani A, Salari M, Talaei MR, Bagheri M, Eskandari Z, J. Environ. Manage., 184, 204 (2016)
  7. Yang Z, Su R, Luo S, Spinney R, Cai M, Xiao R, Wei Z, Sci. Total Environ., 590-591, 751 (2017)
  8. Jepson P, Law R, Science, 352, 1388 (2016)
  9. Ye T, Wei Z, Spinney R, Tang CJ, Luo S, Xiao R, Dionysiou DD, Water Res., 116, 106 (2017)
  10. Premnath N, Mohanrasu K, Rao RGR, Dinesh GH, Prakash GS, Ananthi V, Ponnuchamy K, Muthusamy G, Arun A, Chemosphere, 280, 1 (2021)
  11. Paidi MK, Satapute P, Haider MS, Udikeri SS, Ramachandra YL, Vo DVN, Govarthanan M, Jogaiah S, Environ. Res., 200, 1 (2021)
  12. Chai WS, Cheun JY, Kumar PS, Mubashir M, Majeed Z, Banat F, Ho SH, Show PL, J. Clean Prod., 296, 1 (2021)
  13. Sharma VK, Coord. Chem. Rev., 257, 495 (2013)
  14. Huo C, Dar AA, Nawaz A, Hameed J, Albashar G, Pan B, Wang C, J. King Saud Univ. Sci., 33, 101295 (2021)
  15. Mackul’ak T, Prousek J, Švorc L, Ryba J, Škubák J, Drtil M, Desalination Water Treat., 51, 4489 (2013)
  16. Dar AA, Wang X, Wang S, Ge J, Shad A, Ai F, Wang Z, Chemosphere, 220, 546 (2019)
  17. Hu L, Xia Z, J. Hazard. Mater., 342, 446 (2018)
  18. Pan B, Wu Y, Qin J, Wang C, Catal. Today, 335, 208 (2019)
  19. Li XD, Schwartz FW, J. Contam. Hydrol., 68, 269 (2004)
  20. Hu J, Li Z, Zhang A, Mao S, Jenkinson IR, Tao W, Environ. Res., 188, 1 (2020)
  21. Yngard R, Damrongsiri S, Osathaphan K, Sharma VK, Chemosphere, 69, 729 (2007)
  22. Ciabatti I, Tognotti F, Lombardi L, Desalination, 250, 222 (2010)
  23. Jiang JQ, Lloyd B, Water Res., 36, 1397 (2002)
  24. Jiang Y, Goodwill JE, Tobiason JE, Reckhow DA, Water Res., 96, 114 (2016)
  25. Sharma VK, Luther GW, Millero FJ, Chemosphere, 82, 1083 (2011)
  26. Tiwari D, Lee SM, Ferrate(VI) in the treatment of wastewaters: A new generation green chemical, In: F. S. Garca Einschlag (Ed.). Waste Water - Treatment and reutilization, 241-276, InTech (2011).
  27. Sharma VK, Zboril R, Varma RS, Acc. Chem. Res., 48, 182 (2015)
  28. Delaude L, Laszlo P, J. Org. Chem., 61, 6360 (1996)
  29. Jiang JQ, J. Chem. Technol. Biotechnol., 89, 165 (2014)
  30. Mácová Z, Bouzek K, J. Appl. Electrochem., 41, 615 (2011)
  31. Cañizares P, Sáez C, Sánchez-Carretero A, Rodrigo M, J. Appl. Electrochem., 39, 2143 (2009)
  32. Sharma V, Chen L, Zboril R, ACS Sustain. Chem. Eng., 4 (2015)
  33. Wei YL, Wang YS, Liu CH, Metals, 5, 1770 (2015)
  34. Lee Y, Kissner R, von Gunten U, Environ. Sci. Technol., 48, 5154 (2014)
  35. Sharma VK, Adv. Environ. Res., 6, 143 (2002)
  36. Sharma VK, Liu F, Tolan S, Sohn M, Kim H, Oturan MA, Chem. Eng. J., 221, 446 (2013)
  37. Lee Y, Cho M, Kim JY, Yoon J, J. Ind. Eng. Chem., 10, 161 (2004)
  38. Yang B, Ying GG, Chen ZF, Zhao JL, Peng FQ, Chen XW, Water Res., 62, 211 (2014)
  39. Han Q, Dong W, Wang H, Liu T, Tian Y, Song X, Chemosphere, 198, 92 (2018)
  40. Zhang P, Zhang G, Dong J, Fan M, Zeng G, Sep. Purif. Technol., 84, 46 (2012)
  41. Zhou Z, Jiang JQ, J. Pharm. Biomed. Anal., 106, 37 (2015)
  42. Zhou Z, Jiang JQ, Chemosphere, 119, 95 (2015)
  43. Lalthazuala L, Tiwari D, Lee SM, Choi SS, Appl. Chem. Eng., 32, 340 (2021)
  44. Feng M, Wang X, Chen J, Qu R, Sui Y, Cizmas L, Wang Z, Sharma VK, Water Res., 103, 48 (2016)
  45. Manoli K, Nakhla G, Feng M, Sharma VK, Ray AK, Chem. Eng. J., 330, 987 (2017)
  46. Feng M, Sharma VK, Chem. Eng. J., 341, 137 (2018)
  47. Sun S, Jiang J, Qiu L, Pang S, Li J, Liu C, Wang L, Xue M, Ma J, Water Res., 156, 1 (2019)
  48. Manoli K, Nakhla G, Ray AK, Sharma VK, Chem. Eng. J., 307, 513 (2017)
  49. Ghosh M, Manoli K, Renaud JB, Sabourin L, Nakhla G, Sharma VK, Ray AK, Chemosphere, 230, 416 (2019)
  50. Chen Y, Xiong Y, Wang Z, Chen Y, Chen G, Liu Z, Desalination Water Treat., 55, 1 (2014)
  51. Matafonova G, Batoev V, Water Res., 132, 177 (2018)
  52. Luo C, Feng M, Sharma VK, Huang CH, Environ. Sci. Technol., 53, 5272 (2019)
  53. Aslani H, Nasseri S, Nabizadeh R, Mesdaghinia A, Alimohammadi M, Nazmara S, J. Environ. Manage., 203, 218 (2017)
  54. Mboula VM, Héquet V, Andrès Y, Gru Y, Colin R, Doña-Rodríguez JM, Pastrana-Martínez LM, Silva AMT, Appl. Catal. B: Environ., 162, 437 (2015)
  55. Chuang YH, Szczuka A, Shabani F, Munoz J, Aflaki R, Hammond SD, Mitch WA, Water Res., 152, 215 (2019)
  56. Pan B, Feng M, McDonald TJ, Manoli K, Wang C, Huang CH, Sharma VK, Chem. Eng. J., 398, 1 (2020)
  57. Jiang W, Chen L, Batchu S, Gardinali P, Jasa L, Marsálek B, Zboril R, Dionysiou D, O’Shea K, Sharma V, Environ. Sci. Technol., 48, 12154 (2014)
  58. Zhu X, Li J, Xie B, Feng D, Li Y, Chem. Eng. J., 391, 1 (2020)
  59. Wu S, Liu H, Lin Y, Yang C, Lou W, Sun J, Du C, Zhang D, Nie L, Yin K, Zhong Y, Chemosphere, 244, 1 (2020)
  60. Tian SQ, Wang L, Liu YL, Ma J, Water Res., 183, 116054 (2020)
  61. Zheng L, Cui J, Deng Y, Environ. Sci. Water Res. Technol., 6, 2816 (2020)
  62. Acosta-Rangel A, Sánchez-Polo M, Rozalen M, Rivera-Utrilla J, Polo AMS, Berber-Mendoza MS, López-Ramón MV, J. Environ. Manage., 255, 1 (2020)
  63. Anquandah G, Sharma V, Knight DA, Batchu S, Gardinali P, Environ. Sci. Technol., 45, 10575 (2011)
  64. Barışçı S, Ulu F, Sillanpää M, Dimoglo A, Chem. Eng. J., 262, 1218 (2015)
  65. Eng YY, Sharma VK, Ray AK, Chemosphere, 63, 1785 (2006)
  66. Yang T, Wang L, Liu YL, Zhang W, Cheng HJ, Liu MC, Ma J, Chem. Eng. J., 383, 1 (2020)
  67. Chen B, Xu Z, Ya H, Chen X, Xu M, Acta Oceanol. Sin., 38, 1 (2019)
  68. Czölderová M, Behúl M, Filip J, Zajíček P, Grabic R, Vojs-Staňová A, Gál M, Kerekeš K, Híveš J, Ryba J, Rybanská M, Brandeburová P, Mackuľak T, Chem. Eng. J., 349, 269 (2018)
  69. Rashid SS, Liu YQ, Sci. Total Environ., 756, 1 (2021)
  70. Tijani JO, Fatoba OO, Petrik LF, Water. Air. Soil Pollut., 224, 1 (2013)
  71. Chen J, Qi Y, Pan X, Wu N, Zuo J, Li C, Qu R, Wang Z, Chen Z, Water Res., 158, 338 (2019)
  72. Sailo L, Tiwari D, Lee SM, Sep. Sci. Technol., 52, 2756 (2021)
  73. Li G, Wang N, Liu B, Zhang X, Desalination, 249, 936 (2009)
  74. Xu GR, Zhang YP, Li GB, J. Hazard. Mater., 161, 1299 (2009)
  75. Turkay O, Barışçı S, Dimoglo A, Sep. Sci. Technol., 51, 1924 (2016)
  76. Eskandari Z, Talaiekhozani A, Talaie MR, Banisharif F, J. Environ. Manage., 231, 297 (2019)
  77. Zhu JH, Yan XL, Liu Y, Zhang B, J. Hazard. Mater., 135, 94 (2006)
  78. Wu S, Li H, Li X, He H, Yang C, Chem. Eng. J., 353, 533 (2018)
  79. Liu H, Chen J, Wu N, Xu X, Qi Y, Jiang L, Wang X, Wang Z, Ecotox. Environ. Safe., 170, 259 (2019)
  80. Liu H, Pan X, Chen J, Qi Y, Qu R, Wang Z, Chem. Eng. J., 365, 142 (2019)
  81. Sharma VK, Mishra SK, Ray AK, Chemosphere, 62, 128 (2006)
  82. Sharma VK, Mishra SK, Environ. Chem. Lett., 3, 182 (2006)
  83. Ma Y, Gao N, Li C, Environ. Eng. Sci., 29, 357 (2012)
  84. Jiang JQ, Zhou Z, Patibandla S, Shu X, Microchem J., 110, 239 (2013)
  85. Wang S, Hu Y, Wang J, Sci. Total Environ., 687, 1028 (2019)
  86. Barışçı S, Ulu F, Sillanpää M, Dimoglo A, J. Chem. Technol. Biotechnol., 91, 257 (2016)
  87. Lalthazuala L, Lalhmunsiama, Tiwari D, Lee SM, Ind. J. Biochem. Biophysics, 58, 532 (2021)
  88. Lalhmunsiama, Lalthazuala L, Tiwari D, Environ. Eng. Res., 27(5), 210256 (2021)
  89. Yang B, Ying GG, Zhao JL, Liu S, Zhou LJ, Chen F, Water Res., 46, 2194 (2012)
  90. Tiwari D, Sailo L, Yoon YY, Lee SM, Environ. Eng. Res., 23, 129 (2018)
  91. Lee Y, Zimmermann SG, Kieu AT, von Gunten U, Environ. Sci. Technol., 43, 3831 (2009)
  92. Lee Y, Escher B, Gunten U, Environ. Sci. Technol., 42, 6333 (2008)
  93. Sharma V, Zboril R, McDonald T, J. Environ. Sci. Health Part B-Pestic. Food Contam. Agric. Wastes, 49, 212 (2014)
  94. Karlesa A, De Vera GAD, Dodd MC, Park J, Espino MPB, Lee Y, Environ. Sci. Technol., 48, 10380 (2014)
  95. Casbeer EM, Sharma VK, Zajickova Z, Dionysiou DD, Environ. Sci. Technol., 47, 4572 (2013)
  96. Noorhasan N, Patel B, Sharma VK, Water Res., 44, 927 (2010)
  97. Tiwari D, Sailo L, Yoon YY, Lee S, Environ. Eng. Res., 23, 129 (2017)
  98. Nie J, Yan S, Lian L, Sharma VK, Song W, Water Res., 185, 1 (2020)
  99. Kim C, Panditi VR, Gardinali PR, Varma RS, Kim H, Sharma VK, Chem. Eng. J., 279, 307 (2015)
  100. Lee Y, von Gunten U, Water Res., 44, 555 (2010)
  101. Rivera-Utrilla J, Prados-Joya G, Sánchez-Polo M, Ferro- García MA, Bautista-Toledo I, J. Hazard. Mater., 170, 298 (2009)
  102. Qiang Z, Adams C, Water Res., 38, 2874 (2004)
  103. Ross DL, Riley CM, Int. J. Pharm., 63, 237 (1990)
  104. Jiang JQ, Panagoulopoulos A, Bauer M, Pearce P, J. Environ. Manage., 79, 215 (2006)
  105. Rai PK, Lee J, Kailasa SK, Kwon EE, Tsang YF, Ok YS, Kim KH, Environ. Res., 160, 420 (2018)
  106. Jiang JQ, Wang S, Panagoulopoulos A, Chemosphere, 63, 212 (2006)
  107. Lim M, Kim MJ, Water. Air. Soil Pollut., 200, 181 (2009)
  108. Gombos E, Barkács K, Felföldi T, Vértes C, Makó M, Palkó G, Záray G, Microchem J., 107, 115 (2013)
  109. Deng Y, Jung C, Liang Y, Goodey N, Waite TD, Chem. Eng. J., 334, 2335 (2018)
  110. Tiwari D, Ferrate(VI) a greener solution: Synthesis, characterization, and multifunctional use in treating metal-complexed species in aqueous solution, 161-220, American Chemical Society (2016).
  111. Pachuau L, Lee SM, Tiwari D, Chem. Eng. J., 230, 141 (2013)
  112. Yu MR, Chang YY, Tiwari D, Pachuau L, Lee SM, Yang JK, Desalin. Wat. Treat., 50, 43 (2012)
  113. Tiwari D, Yang JK, Chang YY, Lee SM, Environ. Eng. Res., 13, 131 (2008)
  114. Sailo L, Pachuau L, Yang JK, Lee SM, Tiwari D, Environ. Eng. Res., 20, 89 (2015)
  115. Tiwari D, Sailo L, Pachuau L, Sep. Purif. Technol., 132, 77 (2014)
  116. Lee SM, Diwakar T, J. Environ. Sci., 21, 1347 (2009)
  117. Tiwari D, Kim HU, Choi BJ, Lee SM, Kwon OH, Choi KM, Yang JK, J. Environ. Sci. Health Part A-Toxic/Hazard. Subst. Environ. Eng., 42, 803 (2007)