화학공학소재연구정보센터
홈 로그인 로그아웃 연락처 사이트맵
Journal of Industrial and Engineering Chemistry, Vol.105, 563-570, January, 2022
DOI10.1016/j.jiec.2021.10.016  Export Citation
Integration of dry-reforming and sorption-enhanced water gas shift reactions for the efficient production of high-purity hydrogen from anthropogenic greenhouse gases
Chan Hyun Lee1, 2, Byeong Wan Kwon1, 3, Joo Hyeng Oh1, 4, Suji Kim4, Jonghee Han1, Suk Woo Nam1, Sung Pil Yoon1, Ki Bong Lee4, †, and Hyung Chul Ham5, †
  • 1Center for Hydrogen and Fuel Cell Research, Korea Institute of Science and Technology, 5 Hwarang-ro 14-gil, Seongbuk-gu, Seoul 02792, Republic of Korea
  • 2Clean Fuel Laboratory, Korea Institute of Energy Research, 152 Gajeong-ro, Yuseong-gu, Daejeon 34129, Republic of Korea
  • 3Department of Energy and Chemical Engineering, School of Energy Engineering, Kangwon National University, 346 Joongang-ro Samcheok-si, Kangwon-do 25913, Republic of Korea
  • 4Department of Chemical and Biological Engineering, Korea University, 145 Anam-ro, Seongbuk-gu, Seoul 02841, Republic of Korea
  • 5Department of Chemistry and Chemical Engineering, Education and Research Center for Smart Energy and Materials, Inha University, Incheon 22212, South Korea
E-mail:,
With growing interest in the bulk production of the alternative energy carrier hydrogen, dry-reforming of methane using carbon dioxide has attracted great interest as one of the possible carbon capture and utilization (CCU) technologies and hydrogen production methods. An integrated system combining the dryreforming and water gas shift reactions is suggested to improve the productivity of hydrogen, and a system has also been developed for high-purity hydrogen production from a single system using the sorption-enhanced reaction concept. To realize the proposed system, we develop the Ru-doped Sr0.92Y0.08TiO3 perovskite catalysts and investigate their characteristics using various analyses. The prepared catalysts exhibit excellent CH4 conversion of 92.2% for the dry-reforming reactions at 800 °C without performance degradation by coke formation. Moreover, high-purity hydrogen (>99.5%) is directly produced by the proposed integrated system using anthropogenic greenhouse gases as reactants, and the efficiency is further enhanced by recycling the captured CO2 to the dry-reforming reactor.
Keywords:Perovskite catalyst;Dry-reforming of methane;Sorption-enhanced water gas shift;Integrated system;High-purity hydrogen
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