화학공학소재연구정보센터
Journal of Industrial and Engineering Chemistry, Vol.101, 237-252, September, 2021
Biodegradable hydrogels of cassava starch-g-polyacrylic acid/natural rubber/polyvinyl alcohol as environmentally friendly and highly efficient coating material for slow-release urea fertilizers
E-mail:
Biodegradable semi-IPN hydrogels of cassava starch (CSt)-g-polyacrylic acid (PAA)/natural rubber (NR)/ polyvinyl alcohol (PVA) at different NR/PVA ratios were developed as low-cost coating membrane for improving slow-released fertilizer with low negative impact on environments. The effect of NR/PVA ratios on mechanical properties, swelling behavior, water retention and biodegradation of the semi- IPN hydrogels was evaluated. The biodegradable hydrogel wax coated urea (BHWCU) was produced by coating urea particles with semi-IPN hydrogel and wax as inner and outer layers, respectively. Results revealed that the higher NR/PVA ratios caused the significant decrease in water swelling, modulus, water-retention and biodegradation of the hydrogels. The BHWCU/9:1 formulation exhibited an excellent slow-release N nutrient in both water (47.5% at 168 h) and soil (38.5% at 30 day), relating well with the lowest surface area (1.95 m2/g) and pore volume (3.75 x 10-3 cm3/g). The release kinetics of BHWCUs in both water and soil followed the Korsmeyer-Peppas model. The released nutrient from the BHWCU/9:1 was strongly depended on the pH, temperature and ionic strength. The growth of chili plant was effectively facilitated by the BHWCU/9:1 having 4-5 times lower production cost (80.36 Baht/kg) than commercial slow-release fertilizer. Thus, the BHWCU formulations could be extensively applicable in sustainable agriculture.
  1. Gao J, Liu J, Peng H, Wang Y, Chen S, Lei Z, R. Soc, Open Sci., 5, 5 (2018)
  2. Bortolin A, Aouada FA, Mattoso LHC, Ribeiro C, J. Agric. Food Chem., 61(31), 7431 (2013)
  3. Costa MME, Cabral-Albuquerque ECM, Alves TLM, Pinto JC, Fialho RL, J. Agric. Food Chem., 61(42), 9984 (2013)
  4. Wen P, Wu Z, He Y, Ye BC, Han Y, Wang J, Guan X, A.C.S. Sustain, Chem. Eng., 4(12), 6572 (2016)
  5. Li X, Li Q, Xu X, Su Y, Yue Q, Gao B, J. Taiwan Inst. Chem. Eng., 60 (2016)
  6. Pereira EI, Minussi FB, Cruz CCT, Bernardi ACC, Ribeiro C, Luiz RW, Luiz RW, (2012).
  7. Zhang S, Yang Y, Gao B, Wan Y, Li YC, Zhao C, J. Agric. Food Chem. (2016),
  8. Azeem B, Kushaari K, Man ZB, Basit A, Thanh TH, J. Control. Release, 181(1), 11 (2014)
  9. Ibrahim KRM, Babadi FE, Yunus R, Particuology, 17, 165 (2014)
  10. Rashidzadeh A, Olad A, Carbohydr. Polym., 114, 269 (2014)
  11. Xu XH, Bai B, Ding CX, Wang HL, Suo YR, Ind. Eng. Chem. Res., 54(13), 3268 (2015)
  12. Qiao D, Liu H, Yu L, Bao X, Simon GP, Petinakis E, Chen L, Carbohydr. Polym., 147, 146 (2016)
  13. Zou W, Yu L, Liu X, Chen L, Zhang X, Qiao D, Zhang R, Carbohydr. Polym., 87(2), 1583 (2012)
  14. Riyajan SA, Sasithornsonti Y, Phinyocheep P, Carbohydr. Polym., 89(1), 251 (2012)
  15. Panpinit S, amnart Pongsomboon S, Keawin T, Saengsuwan S, React. Funct. Polym., 156, 104739 (2020)
  16. Liu J, Li Q, Su Y, Yue Q, Gao B, Wang R, Carbohydr. Polym., 94(1), 539 (2013)
  17. Wen P, Han Y, Wu Z, He Y, Ye BC, Wang J, Arab. J. Chem., 10(7), 922 (2017)
  18. Vudjung C, Saengsuwan S, J. Elastomers Plast., 49(7), 574 (2017)
  19. Vudjung C, Saengsuwan S, J. Polym. Environ., 26(9), 3967 (2018)
  20. Tanan W, Panichpakdee J, Saengsuwan S, Eur. Polym. J., 112, 678 (2019)
  21. Chikh L, Delhorbe V, Fichet O, J. Membr. Sci., 368(1-2), 1 (2011)
  22. Xiang Y, Zhang G, Chen C, Liu B, Cal D, Wu Z, A.C.S. Sustain, Chem. Eng., 6, 1192 (2018)
  23. Stelescu MD, Manaila E, Craciun G, Chirila C, Materials, 10(7), 1 (2017)
  24. Zhu B, Ma D, Wang J, Zhang S, Carbohydr. Polym., 133, 448 (2015)
  25. Vudjung C, Chaisuwan U, Pangan U, Chaipugdee N, Boonyod S, Santawitee O, Saengsuwan S, Energy Procedia, 56, 255 (2014)
  26. Tanan W, Panpinit S, Saengsuwan S, Eur. Polym. J., 143, 2021 (2020)
  27. RS PK, AN, AN, PCV, Kalkornsurapranee E, J. Johns, Int. J. Innov. Res. Eng. Manag., (4), 723 (2017).
  28. Lu H, Tian H, Liu Z, Zhang M, Zhao C, Guo Y, Guan R, Chen Q, Yu X, Wang H, Zheng L, ACS Omega, 4(23), 20402 (2019)
  29. Olad A, Zebhi H, Salari D, Mirmohseni A, Tabar A, Mater. Sci. Eng. C-Biomimetic Supramol. Syst., 90, 333 (2018)
  30. Feng C, Lu S, Gao C, Wang X, Xu X, Bai X, Gao N, Liu M, Wu L, A.C.S. Sustain. Chem. Eng., 3, 3157 (2015)
  31. Heuchan SM, Fan B, Kowalski JJ, Gillies EK, Henry HAL, J. Agric. Food Chem., 67(46), 12720 (2019)
  32. Xie LH, Liu MZ, Ni BL, Wang YF, Ind. Eng. Chem. Res., 51(10), 3855 (2012)
  33. Alharbi K, Ghoneim A, Ebid A, El-Hamshary H, El-Newehy MH, Int. J. Biol. Macromol., 116, 224 (2018)
  34. Pang W, Hou D, Wang H, Sai S, Wang B, Ke J, Wu G, Li Q, Holtzapple MT, J. Braz. Chem. Soc., 29(11), 2397 (2018)
  35. Olad A, Gharekhani H, Mirmohseni A, Bybordi A, Adv. Polym. Technol., 37(6), 1682 (2018)
  36. Giroto AS, Guimaraes GG, Colnago LA, Klamczynski A, Glenn G, Ribeiro C, J. Clean Prod., 217, 448 (2019)
  37. Rashidzadeh A, Olad A, Hejazi MJ, Adv. Polym. Technol., 36(2), 177 (2017)
  38. Higuchi T, J. Pharm. Sci., 52, 1145 (1963)
  39. Ritger PL, Peppas NA, J. Control. Release, 5(1), 37 (1987)
  40. Tanan W, Saengsuwan S, J. Environ. Chem. Eng., 8(2) (2020)
  41. Han XZ, Chen S, Hu XG, Desalination, 240(1-3), 21 (2009)
  42. Rozo G, Bohorques L, Santamaria J, Polimeros, 29(3), 2 (2019)
  43. Azeem B, KuShaari K, Naqvi M, Keong LK, Almesfer MK, Al-Qodah Z, Naqvi SR, Elboughdiri N, Polymers, 12, 2 (2020)
  44. Ni B, Liu M, Shaoyu L, Xie L, Wang Y, 10169 (2011).
  45. Olad A, Zebhi H, Salari D, Mirmohseni A, Tabar AR, New J. Chem., 42(4), 2758 (2018)
  46. Wen P, Wu Z, He Y, Ye BC, Han Y, Guan X, Wang J, RSC Adv., 6(44), 37337 (2016)
  47. Xiang YB, Zhang GL, Chi Y, Cai DQ, Wu ZY, Chem. Eng. J., 328, 320 (2017)