화학공학소재연구정보센터
KAGAKU KOGAKU RONBUNSHU, Vol.46, No.5, 167-175, 2020
Hydrothermal Organic Acid Leaching of Positive Electrode Material of Lithium-Ion Batteries
To construct a recycling process for spent lithium-ion batteries, the hydrothermal leaching by organic acid of lithium-ion battery positive electrode materials and spent lithium-ion batteries was examined by treatment with citric acid (0.4. 2.0 mol/dm(3)) at 80-200 degrees C for 5-60 min. Leaching efficiencies of Li, Co and Ni were found to increase with increasing reaction temperature and time. The leaching efficiency of Mn was more than 90% under mild conditions of 110 degrees C for 5 min, but it decreased as the reaction temperature increased, and a white solid precipitated. However, when the temperature was further increased, the leaching efficiency increased again. When the eThect of reaction temperature on leaching efficiency was investigated with spent lithium-ion batteries, the positive electrode elements Li, Co, Ni and Mn were all leached. Furthermore, it was suggested that in the leaching of spent lithium-ion batteries, the crystal structure of the positive electrode elements was changed by the pretreatment, which affected the leaching mechanism.