화학공학소재연구정보센터
Journal of Colloid and Interface Science, Vol.587, 141-149, 2021
Walnut kernel-like iron-cobalt-nickel sulfide nanosheets directly grown on nickel foam: A binder-free electrocatalyst for high-efficiency oxygen evolution reaction
Developing earth-rich and high-efficiency nonprecious metal catalysts is critical but extremely challenging for oxygen evolution reaction (OER). Herein, a simple room-temperature sulfuration method was developed for in situ synthesis of walnut kernel-like iron-cobalt-nickel sulfide nanosheets on nickel foam (FeCoNiSx/NF). The unique nanosheets exposed abundant active sites and provided large electrochemically active surface area. The as-built FeCoNiSx/NF exhibited high OER performances with the small over potentials of 231 and 268 mV to afford 10 and 50 mA cm(-2) in 1.0 M KOH, respectively, coupled with a small Tafel slope of 55 mV dec(-1). Furthermore, the FeCoNiSx/NF acted as the anode towards overall water electrolysis with acceptable results, where commercial Pt/C dropped on the NF worked as the cathode. This study provides some valuable insights for rational construction of nonprecious electrocatalysts in electrochemical energy technologies. (c) 2020 Elsevier Inc. All rights reserved.